Synthesis and magnetic property of a nitroxide based on C60 被引量：1

Synthesis and magnetic property of a nitroxide based on C60

下载PDF

导出

摘要 The compounds containing stable nitroxide radicals possess magnetic properties for the free radical have net magnetic moment. Oxidization of the [60]fulleropyrolidine obtained from the reaction of C60 with diketone and 2-aminoisobutyric acid by m-chloroperoxybenzoic acid gives a new nitroxide integrated with C60. The stable nitroxide based on C60 is confirmed to be antiferro-magnetism with quantum design superconducting quantum interference device (SQUID). The compounds containing stable nitroxide radicals possess magnetic properties for the free radical have net magnetic moment. Oxidization of the [60]fulleropyrolidine obtained from the reaction of C60 with diketone and 2-aminoisobutyric acid bym- chloroperoxybenzoic acid gives a new nitroxide integrated with C60. The stable nitroxide based on C60 is confirmed to be antiferro-magnetism with quantum design superconducting quantum interference device (SQUID).

作者 Zhiqiang Shi Yuliang Li Zhongxin Ge Daoben Zhu

机构地区 Chinese Acad Sci

出处《Chinese Science Bulletin》 SCIE EI CAS 2000年第10期896-899,共4页

关键词 FERROMAGNET FULLERENE NITROXIDE 1 3-dipolar circle ADDITION reaction. ferromagnet fullerene nitroxide 1,3-dipolar circle addition reaction

分类号 O613.71 [理学—无机化学]

引文网络
相关文献

参考文献1

1LI Yuliang, ZHENG Dagui, XU Juhua, MAO Zhong, YANG Jingkui, BAI Fenglian and ZHU DaobenInstitute of Chemistry, Chinese Academy of Sciences, Beijing 100080, China.Synthesis of fulleropyrrolidine derivatives of C_(60)[J].Chinese Science Bulletin,1997,42(14):1180-1184. 被引量：3

共引文献2

1郑大贵,肖竹平,李玉良.一个由α-氨基酸和酮产生卡宾的新反应[J].有机化学,2007,27(12):1609-1611.
2Zhiqiang Shi,Yuliang Li,Shu Wang,Hongjuan Fang,Daoben Zhu.Synthesis and antioxidative properties of polyphenol-fullerenes[J].Chinese Science Bulletin,2001,46(21):1790-1792. 被引量：2

同被引文献3

1LI Yuliang, ZHENG Dagui, XU Juhua, MAO Zhong, YANG Jingkui, BAI Fenglian and ZHU DaobenInstitute of Chemistry, Chinese Academy of Sciences, Beijing 100080, China.Synthesis of fulleropyrrolidine derivatives of C_(60)[J].Chinese Science Bulletin,1997,42(14):1180-1184. 被引量：3
2ZHANG YongzhengDepartment of Mathematics, Northeast Normal University, Changchun, 130024, China.Finite-dimensional Lie superalgebras of Cartan type over fields of prime characteristic[J].Chinese Science Bulletin,1997,42(9):720-724. 被引量：74
3Sun, DY,Zhu, YS,Liu, ZY,Liu, GZ,Guo, XH,Zhan, RY,Liu, XY.Active oxygen radical scavenging ability of water-soluble fullerenols[J].Chinese Science Bulletin,1997,42(9):748-752. 被引量：1

引证文献1

1Zhiqiang Shi,Yuliang Li,Shu Wang,Hongjuan Fang,Daoben Zhu.Synthesis and antioxidative properties of polyphenol-fullerenes[J].Chinese Science Bulletin,2001,46(21):1790-1792. 被引量：2

二级引证文献2

1刘广,罗友谊,唐宇龙,印遇龙.富勒烯[C_(60)]抗氧化应激的研究进展及在畜禽生产中的应用前景[J].动物营养学报,2022,34(1):59-67.
2黎小青,朱晟,韩鄂宁,刘雅玲,张婧芳,王贵弘.羟基富勒烯在抵抗皮肤光老化中发挥的功效[J].广东化工,2022,49(15):25-29. 被引量：1

1Tao GU,Chun TANG,Zhu De XU(Department of Chemistry, Zhejiang University, Hangzhou 310027).Synthesis of C_(60) Nitroxide Derivatives[J].Chinese Chemical Letters,1999,10(2):95-96.
2王玉芳,张永花,王利亚.Synthesis, Crystal Structure and Magnetic Properties of a Novel Azide-bridged Copper(Ⅱ) Coordination Polymers Containing Nitroxy Nitroxide[J].Chinese Journal of Structural Chemistry,2011,30(9):1322-1326. 被引量：1
3郑大贵,李玉良,范楼珍,李凤英,李永舫,朱道本.1,3-Dipolar cycloaddition reaction of two different azomethine ylides to C70[J].Chinese Journal of Chemistry,1998,16(2):178-183.
4Zhou, SF,Su, JY,Zeng, LM.1,3-Dipolar Cycloaddition Reaction between Vinyl Acetate and N-Alkyl Hydroxypyridinium Halide[J].Chinese Chemical Letters,2001,12(12):1053-1054.
5Man LU,Jian Guo FANG,Zhong Li LIU,Long Min WU.Novel Reaction of Nitroxide with Hantzsch Dihydropyridines[J].Chinese Chemical Letters,2002,13(10):923-925.
6刘力生,郑荣梁,HAROLD M. SWARTZ,张自义,魏陆林.DNA SYNTHESIS INHIBITION OF NITROXIDE RADICALS ON LEUKEMIA CELLS[J].Science China Chemistry,1991,34(9):1063-1069.
7张翱,阚颖,姜标.Asymmetric 1,3-dipolar cycloaddition of nitrile oxides to chiral acryloyl esters bearing glucofuranose as auxiliary[J].Chinese Journal of Chemistry,2000,18(2):220-224.
8Zheng, DG,Li, YL,Mao, Z,Zhu, DB.Study on the reaction of C60 with DL-valine and cyclohexanone[J].Chinese Journal of Chemistry,1996,14(6):555-560.
9MA Yue, CHEN XiaoPing, CAO Dong, YAN ShiPing & LIAO DaiZheng Department of Chemistry, Nankai University, Tianjin 300071, China.Structure and magnetic properties of a novel heterospin 1-D chain complex containing both Cu(Ⅱ) and nitroxide radicals as spin branches[J].Science China Chemistry,2009,52(9):1438-1443. 被引量：2
10姜标,张翱,阚颖.Asymmetric 1,3-dipolar cycloaddition of nitrile oxides with optically active vinylboronic ester[J].Chinese Journal of Chemistry,1999,17(3):293-299.

Chinese Science Bulletin

2000年第10期

浏览历史

内容加载中请稍等...