摘要
This paper reports a simple and highly selective method for preconcentrating and separating of trace Pd(II) and Pt(IV) with silica gel bonded by aminopropyl-benzoylazo-4-(2-pyridylazo)-resorcinol (ABPR·SG). ABPR·SG is stable in solution from 6 mol/L HCl to pH 7.0 and in common organic solvents. The maximum adsorptive capacity of Pd(II) on ABPRSG is 362 μmol/g. After preconcentrating and separation by using ABPR·SG column, Pd(II) and Pt(IV) of μg/L level in artificial water samples can be measured reliably by common spectrophotometer. The maximum concentration factors of Pd(II) and Pt(IV) on ABPR·SG column are 143 and 125 respectively. The chromatographic column packed with ABPR·SG can be reused. The method is simple and efficient.
This paper reports a simple and highly selective method for preconcentrating and separating of trace Pd(II) and Pt(IV) with silica gel bonded by aminopropyl-benzoylazo-4-(2-pyridylazo)-resorcinol (ABPR·SG). ABPR·SG is stable in solution from 6 mol/L HCl to pH 7.0 and in common organic solvents. The maximum adsorptive capacity of Pd(II) on ABPRSG is 362 μmol/g. After preconcentrating and separation by using ABPR·SG column, Pd(II) and Pt(IV) of μg/L level in artificial water samples can be measured reliably by common spectrophotometer. The maximum concentration factors of Pd(II) and Pt(IV) on ABPR·SG column are 143 and 125 respectively. The chromatographic column packed with ABPR·SG can be reused. The method is simple and efficient.
基金
Project (No. 2932009) supported by the Natural Science Foundation of Beijing.
