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Preparation and Characterization of Layered Compound Zirconium Bis(monohydrogenphosphate) Intercalated with Rare Earth Complex

Preparation and Characterization of Layered Compound Zirconium Bis(monohydrogenphosphate) Intercalated with Rare Earth Complex
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摘要 Layered compound zirconium bis(monohydrogenphosphate)(alpha-ZrP) intercalated with rare earth complex Eu(DBM)(3)phen was prepared. The pre-intercalation of p-methoxyaniline into alpha-ZrP makes the interlayer separation large enough to exchange PMA with europium complex, thus, the luminescent assembly was prepared. This was confirmed by X-ray diffraction, UV-visible spectra and elemental analysis. The fluorescence spectra and lifetime of the assembly were also presented. Layered compound zirconium bis(monohydrogenphosphate)(alpha-ZrP) intercalated with rare earth complex Eu(DBM)(3)phen was prepared. The pre-intercalation of p-methoxyaniline into alpha-ZrP makes the interlayer separation large enough to exchange PMA with europium complex, thus, the luminescent assembly was prepared. This was confirmed by X-ray diffraction, UV-visible spectra and elemental analysis. The fluorescence spectra and lifetime of the assembly were also presented.
出处 《Chinese Chemical Letters》 SCIE CAS CSCD 2000年第2期171-174,共4页 中国化学快报(英文版)
关键词 layered compound rare earth complex LUMINESCENCE layered compound rare earth complex luminescence
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参考文献3

  • 1L. R. Matthews,E. T. Knobbe,Chem. Mater . 1993
  • 2A. Clearfleld,J. A. Stynes,J. Inorg. Nucl. Chem . 1964
  • 3M. B. Dines,P. M. Digiacomo,Inorg. Chemtracts . 1981

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