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Sulphidation of Fe-Nb,Co-Nb and Ni-Nb Alloys in H_2-H_2S at 700℃

Sulphidation of Fe-Nb,Co-Nb and Ni-Nb Alloys in H_2-H_2S at 700℃
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摘要 The corrosion of alloys based on Fe,Co and Ni containing 15 and 30 wt-% Nb was studied at 700℃ in H_2-H_2S mixtures providing 10^(-8) atm S_2.The Fe and Co-based alloys formed duplex scales with an outer layer of pure base-metal sulphide and an inner layer containing both metals.The Nb addi- tions were not able to produce exclusive Nb sulphidation but yielded a significant decrease of the corrosion rates for both types of alloys with respect to the pure metals even though they were still much higher than that of pure Nb.The Ni-base alloys corroded rapidly forming a single complex scale layer,mainly due to the appearance of a liquid Ni-S solution. The corrosion of alloys based on Fe,Co and Ni containing 15 and 30 wt-% Nb was studied at 700℃ in H_2-H_2S mixtures providing 10^(-8) atm S_2.The Fe and Co-based alloys formed duplex scales with an outer layer of pure base-metal sulphide and an inner layer containing both metals.The Nb addi- tions were not able to produce exclusive Nb sulphidation but yielded a significant decrease of the corrosion rates for both types of alloys with respect to the pure metals even though they were still much higher than that of pure Nb.The Ni-base alloys corroded rapidly forming a single complex scale layer,mainly due to the appearance of a liquid Ni-S solution.
出处 《Journal of Materials Science & Technology》 SCIE EI CAS CSCD 1993年第3期167-171,共5页 材料科学技术(英文版)
关键词 NIOBIUM ALLOYS sulphidation high temperature niobium alloys sulphidation high temperature
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参考文献6

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