摘要
4'R, Z, 2-(4'-hydroxy-2'-nonenyl)-1,3-dioxane 2 which is an intermediate in the synthesis of chiral δ-lactones, has been syntheslzed from dlepoxide 3. Enantioselective total synthesis of 6R-(-)-massoialactone 1 has been achieved from 2 through 4 steps
4'R, Z, 2-(4'-hydroxy-2'-nonenyl)-1,3-dioxane 2 which is an intermediate in the synthesis of chiral δ-lactones, has been syntheslzed from dlepoxide 3. Enantioselective total synthesis of 6R-(-)-massoialactone 1 has been achieved from 2 through 4 steps.
