摘要
本文用AOM(角重叠模型)的近似方法,计算了各种电子构型的八面体和平面四方形配合物的MOSE,得出了八面体配合物的畸变倾向于四方畸变的结论。用此方法还能预测一些姜一太勒定理不能预测的配合物的几何构型。
Using the approximate method of AOM (Angle Overlap Model) , the paper calculates the MOSE (Molecular Orbit Energy) of coodinat-ion compounds of octahedron and tetragon of various eletronic configudr-ations.The calculation comes to the conclusion that the distortion of the coordinatioh compound of octahedron tends towards tetragonal distortion, This method can also be used to calculate some geomctrical configurations of the coordination which H.A. Jahn's and E.Teller's theorems cannot calculate.
出处
《赣南师范学院学报》
1990年第S1期64-68,共5页
Journal of Gannan Teachers' College(Social Science(2))
关键词
八面体配合物
畸变
AOM应用
coordination compounds of octahedron , distortion , AOM applioation.
