摘要
芳香氮磷杂五元环是环状二配位磷化合物中的一类,近年来已有综述报道。1,2,3σ~2-二氮磷杂环戊二烯首先由Ignatova提出。
A series of two-coordinate phosphorus compounds 2-(Aryloxyphenylthiophosphonyl)-1, 2, 3σ~2-Diazaphospholes (4) have been prepared by dehydrohalogenation of the 2-(Aryloxyphenylthiophosphonyl)-3-chlor-1, 2, 3-Diazaphospholine (3). They were synthesizedthrough the reaction of Aryloxyphenylthiophosphonylhydrazones (2) with PCl_3. The structuresof these new compounds have been confirmed by elemental analysis, IR, ~1H NMR, ^(31)P NMRand MS.
出处
《有机化学》
SCIE
CAS
CSCD
北大核心
1990年第4期353-357,共5页
Chinese Journal of Organic Chemistry
基金
南开大学元素有机化学国家重点实验室资助
关键词
二氮磷杂
环戊二烯
环戊烯
合成
two-coordinate phosphorus compound
diazaphosphole
hydrazone
diazaphospholine
