摘要
反钙钛矿结构锰氮化合物是近年发展起来的一类具有各向同性、负热膨胀系数及负热膨胀温度区间可调、金属性能及力学性能优良的新型负热膨胀材料,展现出重要的应用潜力.本文从负热膨胀材料的发展历史、化合物体系、制备方法、负热膨胀性能影响因素及微观机理等方面,阐述了反钙钛矿结构锰氮化合物负热膨胀材料的研究现状及最新发展动态,并对其发展前景进行了分析和展望.
Antiperovskite manganese nitrides are a group of negative thermal expansion(NTE) materials that have been developed rapidly in recent years.They exhibit important potential applications due to isotropic NTE property,controllable coefficient of NTE and NTE operation temperature window,and good metallic and mechanical properties.In this review,state of the arts and recent development in the field of studying antiperovskite manganese nitrides have been summarized and commented,which consist of introduction of history,classification,preparation approaches,influencing factors and mechanisms of NTE for such materials.The prospects are also described for antiperovskite manganese nitrides.
出处
《金属学报》
SCIE
EI
CAS
CSCD
北大核心
2011年第11期1362-1371,共10页
Acta Metallurgica Sinica
基金
国家重点基础发展计划项目2011CB612207
北京市自然科学基金项目2112006资助~~
关键词
负热膨胀
零膨胀
反钙钛矿结构
锰氮化合物
negative thermal expansion
zero thermal expansion
antiperovskite structure
manganese nitride