摘要
以苯乙酮为原料,氯化亚砜-无水乙醇体系作催化剂,合成了1,3,5-三苯基苯.用二硫化碳-无水三氯化铝作催化剂,合成了13,,5-三(4-乙酰基苯基)苯.在稀碱的催化下,1,35,-三(4-乙酰基苯基)苯与苯甲醛反应,进一步合成了1,35,-三(4-(苯丙烯酰基)苯基)苯.采用傅立叶红外光谱和核磁共振(1H-NMR)对目标产物进行表征并得到了一致的结果.
1,3,5-triphenylbenzene was synthesized using acetophenone as raw material and anhydous thionyl chloride in ethanol as catalyst,. Then 1,3,5-tri （4-acetylphenyl） benzene was synthesized using anhydrous carbon disulfide-AlCl3 as catalyst. In the presence of a dilute base catalyst, 1,3,5-tri（4-（phenylacryloyl） phenyl） benzene was obtained from 1,3,5- tri（4-acetylphenyl） benzene and benzaldehyde. These compounds have been characterized by FT-IR and 1H-NMR.
出处
《中南民族大学学报（自然科学版）》
CAS
2011年第4期23-25,共3页
Journal of South-Central University for Nationalities：Natural Science Edition
