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Synthesis and Crystal Structure of 8-Methyl-7-(3-nitrophenyl)-10-phenyl-10,11-dihydrochro-meno[4,3-b]pyrazolo[4,3-e]pyridin-6-(7H)-one

Synthesis and Crystal Structure of 8-Methyl-7-(3-nitrophenyl)-10-phenyl-10,11-dihydrochro-meno[4,3-b]pyrazolo[4,3-e]pyridin-6-(7H)-one
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摘要 The title compound(C26H18N4O4) has been synthesized via a three-component reaction and it was characterized by means of IR and 1H NMR.Its crystal and molecular structures were determined by X-ray diffractometry.It belongs to the triclinic system,space group P1 with a = 7.7288(15),b = 11.168(2),c = 12.645(3) ,α = 107.02(3),β = 90.85(3),γ = 101.93(3)°,V = 1017.9(3) 3,Mr = 450.44,Z = 2,Dc = 1.470 g/cm3,λ = 1.54178 ,μ = 0.836 mm-1,F(000) = 468,the final R = 0.0488 and wR = 0.1180.A total of 11903 reflections were collected,of which 3642 were independent(Rint = 0.0377) and 3025 were observed with I 2σ(I). The title compound(C26H18N4O4) has been synthesized via a three-component reaction and it was characterized by means of IR and 1H NMR.Its crystal and molecular structures were determined by X-ray diffractometry.It belongs to the triclinic system,space group P1 with a = 7.7288(15),b = 11.168(2),c = 12.645(3) ,α = 107.02(3),β = 90.85(3),γ = 101.93(3)°,V = 1017.9(3) 3,Mr = 450.44,Z = 2,Dc = 1.470 g/cm3,λ = 1.54178 ,μ = 0.836 mm-1,F(000) = 468,the final R = 0.0488 and wR = 0.1180.A total of 11903 reflections were collected,of which 3642 were independent(Rint = 0.0377) and 3025 were observed with I 2σ(I).
出处 《Chinese Journal of Structural Chemistry》 SCIE CAS CSCD 2012年第1期57-60,共4页 结构化学(英文)
基金 Project supported by the National Natural Science Foundation of China (No. 81071144) Natural Science Foundation of Guangdong Province (No. 9451806001002961)
关键词 multicomponent reaction coumarin derivatives crystal structure multicomponent reaction coumarin derivatives crystal structure
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