摘要
采用传统固相合成法制备了锆掺杂的钛酸钡陶瓷Ba(Zr0.15Ti0.85)O3(BZT),并对其介电性能进行了研究.发现1 280℃烧结的BZT陶瓷的介电性能呈现明显的弥散性相变和弛豫特点.用Smolenski成分起伏理论结合德拜弛豫理论计算了BZT的介电常数峰值εrm与频率的关系,与实验结果吻合较好.
Barium zirconium titanate Ba(Zr0.15Ti0.85)O3(BZT) ceramic was prepared via the traditional solid state reaction and its dielectric properties were studied.The BZT ceramic sintered at 1 280 ℃obviously showed dielectric characteristics with diffuse phase transition and relaxation.The frequency dependence of maximum of dielectric constant had been obtained by integrating Smolenski theory with the Debye relaxation theory.The theoretical results agreed well with the experimental data.
出处
《河南大学学报(自然科学版)》
CAS
北大核心
2012年第1期17-19,23,共4页
Journal of Henan University:Natural Science
基金
国家自然科学基金资助项目(50972056)
河南科技大学科研创新能力培育基金项目(2010CZ20017)
关键词
固相法
BZT陶瓷
相变弥散
介电弛豫
solid state reaction
BZT ceramic
dielectric relaxation
diffusive phase transition