摘要
以油酸镍和三(三苯基膦)二氯化钌为催化剂对均相催化裂解生物油中的低聚物进行试验研究。结果表明:油酸镍的催化效果优于三(三苯基膦)二氯化钌。当以油酸镍为催化剂时,较佳的反应条件为:反应温度150℃、反应时间24h、催化剂与生物油低聚物质量比R催化剂/低聚物=0.034,在此条件下二氧化碳生成量为4.43mmol,粘度从4.16mm2/s下降到3.49mm2/s;催化精制后,气相质谱联用仪可检测到的酚类物质含量基本都较之前有所增加。
The experimental study of homogeneous catalytic cracking bio-oil oligomer with nickel oleate and RuC12（PPh3）3 was investigated. The results indicated that the catalytic effect of nickel oleate better than RuClz（PPh3）3. The optimal reaction conditions were obtained as follows： reaction temperature 150℃, reaction time 24h, the mass ratio of catalyst to bio-oil oligomer is 0. 034, nickel oleate as catalyst. In the optimum operation conditions, the amount of carbon dioxide reached 4.43mmol, and viscosity was lowered from 4.16mm2/s to 3.49mm2/s. The results showed that the content of phenolic compounds which could be detected by GC-MS increased.
出处
《太阳能学报》
EI
CAS
CSCD
北大核心
2012年第1期153-157,共5页
Acta Energiae Solaris Sinica
基金
国家高技术研究发展(863)计划(2009AA05Z406)
国家自然科学基金(5087609950906077)
关键词
生物油
生物油低聚物
均相催化
催化裂解
bio-oil
bio-oil oligomer
homogeneous catalysis
catalytic cracking
