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Effects of aluminum additive on diamond crystallization in the Fe-Ni-C system under high temperature and high pressure conditions 被引量:3

Effects of aluminum additive on diamond crystallization in the Fe-Ni-C system under high temperature and high pressure conditions
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摘要 In this paper, we investigate diamond crystallization in Fe-Ni-C with an aluminum additive and the capability of aluminum for converting graphite to diamond in a series of experiments at 4.9-5.5 GPa and 1240-1500℃. Our experimental results show that the growth habits of diamond crystal have been significantly influenced by the addition of aluminum as a catalyst. The crystal color changes from yellow to nearly colorless. The morphology of the synthesized diamond crystals gradually changes from cubic-octahedron to octahedron in the Fe-Ni-C systems with increasing aluminum additive. The lowest synthesis conditions fell first and then rose with increasing aluminum. We found a suitable addition of aluminum is very effective in lowering the synthesis conditions while an excessive aluminum additive may have a suppressive effect on the diamond nucleation. In this paper,we investigate diamond crystallization in Fe-Ni-C with an aluminum additive and the capability of aluminum for converting graphite to diamond in a series of experiments at 4.9-5.5 GPa and 1240-1500°C.Our experimental results show that the growth habits of diamond crystal have been significantly influenced by the addition of aluminum as a catalyst.The crystal color changes from yellow to nearly colorless.The morphology of the synthesized diamond crystals gradually changes from cubic-octahedron to octahedron in the Fe-Ni-C systems with increasing aluminum additive.The lowest synthesis conditions fell first and then rose with increasing aluminum.We found a suitable addition of aluminum is very effective in lowering the synthesis conditions while an excessive aluminum additive may have a suppressive effect on the diamond nucleation.
出处 《Science China(Physics,Mechanics & Astronomy)》 SCIE EI CAS 2012年第5期781-785,共5页 中国科学:物理学、力学、天文学(英文版)
基金 supported by the New Century Excellent Talents in University and the National Natural Science Foundation of China (Grant Nos.50572032,50731006 and 50801030)
关键词 crystal morphology DIAMOND aluminum additive 金刚石晶体 合金添加剂 C系统 除铝 高压条件 结晶 高温 合成条件
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