期刊文献+

毛细管离子色谱法测定酒和饮料中阳离子 被引量:9

Determination of cations in wines and beverages based on capillary ion chromatography
下载PDF
导出
摘要 建立了毛细管离子色谱测定酒、饮料等样品中阳离子的分析方法。使用毛细管离子色谱柱IonPac CS12A(250 mm×0.4 mm,8μm),以甲基磺酸淋洗液发生器(EGC-MSA)产生18 mmol/L的甲基磺酸为流动相,进样量0.4μL,在流速0.01 m L/m in的条件下,采用自循环抑制电导检测的方法对啤酒、葡萄酒、白酒、果汁及奶茶等样品中的阳离子含量进行检测。结果表明,毛细管离子色谱法能满足阳离子含量的测定要求,系统稳定不易堵,在灵敏度方面优于常规离子色谱系统。该方法能够快速、准确地测定酒、饮料等样品中的5种阳离子(钠、铵、钾、镁和钙),回归方程的相关系数在0.999 7以上,实际样品的加标回收率为95.2%~103.3%。该方法具有灵敏度高,操作简单,环境友好的特点。 A new method for the determination of five cations(sodium,ammonium,potassium,magnesium and calcium) in wines and beverages was developed and validated based on capillary ion chromatography.With a capillary ion exchange column(IonPac CS12A,250 mm×0.4 mm,8 μm) and 18 mmol/L methanesulfonic acid(MSA) elution,the five cations can be well separated in 15 min.After suppression with a capillary suppressor(CCES 300),the background was much decreased,and the sensitivities of the cations were greatly improved.For the milky tea,acetonitrile was added into the sample solution to deposit the proteins.With the pretreatment of an OnGuard RP cartridge to remove hydrophobic substances in the sample,the developed method can be applied to the determination of the cations in wines and beverages.The calibration curves of peak area versus concentration gave correlation coefficients more than 0.999 7 for these cations.Average recoveries were between 95.2%-103.3%.The method is suitable for the determination of alkali metals and alkaline-earth metals in wines and beverages.The capillary ion chromatography provides analysis with less solvent consumption and better column efficiency,also possesses the advantages of high sensitivity,good selectivity and environmental friendly.
出处 《色谱》 CAS CSCD 北大核心 2012年第4期400-403,共4页 Chinese Journal of Chromatography
基金 安徽省教育厅高校省级科学研究项目(KJ2011B211)
关键词 毛细管离子色谱 抑制电导检测 阳离子 饮料 capillary ion chromatography(CIC) suppressor conductivity detection cations wines beverages
  • 相关文献

参考文献12

  • 1牟世芬;刘克纳;丁晓静.离子色谱方法及应用[M]北京:化学工业出版社,20056.
  • 2叶明立,潘广文,胡忠阳,汪琼.离子色谱法测定婴幼儿配方奶粉中的核苷酸[J].色谱,2010,28(9):898-901. 被引量:22
  • 3史亚力;刘京生;蔡亚岐.查看详情[J]分析化学,2005(05):605.
  • 4Shaw M J;Haddad P R.查看详情[J],Environment International2004(03):403.
  • 5Saccani G,Tanzi E,Pastore P. Determination of biogenic amines in fresh and processed meat by suppressed ion chromatography-mass spectrometry using a cation-exchange column[J].Journal of Chromatography A,2005,(01):43.doi:10.1016/j.chroma.2005.05.030.
  • 6Hu Z Z;Zhong Y Y;Chang Y.查看详情[J],Chinese Chemical Letters2009(05):1498.
  • 7Zhu Y,Guo Y Y,Ye M L. Preparation of novel hollow mesoporous silica spheres and their sustained-release property[J].Journal of Chromatography A,2005,(03):143.doi:10.1088/0957-4484/16/11/027.
  • 8Burgess K;Creek D;Dewsbury P.查看详情[J],Rapid Communications in Mass Spectrometry2011(22):3447.
  • 9Ng B K;Shellie R A;Dicinoski G W.查看详情[J],Journal of Chromatography A2011(32):5512.
  • 10叶明立,胡忠阳,潘广文.毛细管离子色谱法同时测定饮用水中痕量碘离子、硫氰酸根和草甘膦[J].分析化学,2011,39(11):1762-1765. 被引量:27

二级参考文献22

共引文献82

同被引文献148

引证文献9

二级引证文献71

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部