摘要
针对目前中国常规固井降失水剂抗温抗盐能力差、综合性能欠佳的问题,以2-丙烯酰胺基-2-甲基丙磺酸(AMPS)、N,N-二甲基丙烯酰胺(DMAA)、新型双羧基化合物为单体,采用水溶液自由基聚合的方法合成了耐盐、抗高温的共聚物型固井水泥降失水剂HTF-200C。HTF-200C微观结构表征和应用性能综合评价表明,各单体成功参与聚合,共聚物热稳定性良好;该降失水剂控失水耐温可达200℃,抗盐达饱和,可解决常规降失水剂高温下易水解、稠化实验"鼓包"等问题;以HTF-200C为主剂的水泥浆体系失水量低、抗盐耐温能力强、低温下强度发展快、无超缓凝现象、胶凝强度过渡时间短,具有很好的综合性能。产品在辽河油田陈古1-3井应用后固井质量达到优质。
The domestic fluid loss additives often have lower thermal stability and poor salt-tolerance and their comprehensive properties are not good enough.To solve the problems,a novel cement fluid loss additive HTF-200C,which can resist high temperature and high salt content,was synthesized using the monomers of 2-acrylamido-2-methyl-propane sulphonic acid（AMPS）,N,N-dimethyl acrylamide（DMAA） and a new compound with double carboxyl by the method of aqueous solution polymerization.The microstructural characterization and application performance of HTF-200C show that the polymer with the structure of all the monomers has an excellent thermal stability and strong salt tolerance,and can be used in 200 ℃ or in saturated brine.And the problem of the normal fluid loss additive being easy to hydrolyze due to high temperature can be solved with HTF-200C.What’s more,it can also deal with the bulge of thickening curve in consistency test.The cement slurry prepared mainly by HTF-200C presents good comprehensive properties such as low filtration,high thermal stability,strong salt tolerance,rapid development of strength in low temperature,without far delayed solidification,short transit time during thickening process,and so on.The cementing job quality of Well Chengu 1-3 in the Liaohe Oilfield is excellent after it is used.
出处
《石油勘探与开发》
SCIE
EI
CAS
CSCD
北大核心
2012年第3期359-364,共6页
Petroleum Exploration and Development
基金
国家科技重大专项(2008ZX05021
2008ZX05021-004)
