摘要
综述了氧化硝化法、氯化硝化法、铁氰化钾路线、电化学法等合成2,2–二硝基丙醇(DNPOH)的进展,并且比较了它们的特点,最后提出了洁净的电化学法是很有前途的绿色合成方法。另外,简述了DNPOH作为关键中间体在合成含能增塑剂和含能黏合剂中的应用情况。
The progress in synthesis of 2,2-dinitropropanol (DNPOH) by oxidative nitrating method, chlorinating nitrating method, potassium ferricyanide route and electrochemical method is reviewed, and their characteristics are compared. At last, it is pointed out that the clean electrochemical method is a promising green synthesis method. In addition, the application situations of DNPOH as a key intermediate in synthesis of energetic plasticizers and binders are briefly described.
出处
《化学推进剂与高分子材料》
CAS
2012年第3期32-36,42,共6页
Chemical Propellants & Polymeric Materials