摘要
合成了环糊精二聚体(trans-Azoβ-CD Dimer)及侧链含金刚烷(Ad)的聚丙烯酰胺(PAM-Ad),利用trans-Azoβ-CD Dimer与PAM-Ad侧链的Ad基团的主客体识别作用构筑了一类超分子体系。2D NMR测定结果表明,trans-Azoβ-CD Dimer和PAM-Ad的主客体相互作用是通过β-CD空腔和疏水体Ad形成包结络合物进行的。环糊精二聚体trans-Azoβ-CD Dimer和聚合物PAM-Ad两者之间的缔合程度受trans-Azoβ-CD Dimer和PAM-Ad的浓度、温度、盐浓度以及trans-Azoβ-CD Dimer光异构的影响。
Cyclodextrin dimer（ trans-Azo β-CD Dimer） and adamantyl modified polyacrylamide（ PAM- Ad） were synthesized. A supramolecular system was constructed by the formation of inclusion complex between trans-Azo β-CD Dimer and PAM-Ad. The results of 2D NMR measurement indicate that the host-guest interaction between trans-Azo β-CD Dimer and PAM-Ad was carried out through the formation of inclusion complexes between β-CD cavity and the hydrophobe Ad. The interaction between trans-Azo fl-CD Dimer and PAM-Ad depended on the concentration of trans-Azo β-CD Dimer, PAM-Ad and the photoisomerization of trans-Azo /3-CD Dimer. The influences of salt concentration and temperature on the viscosity of the mixture solution were also studied.
出处
《精细化工》
EI
CAS
CSCD
北大核心
2012年第6期531-536,共6页
Fine Chemicals
基金
国家自然科学基金(21176004)
北京市教育委员会科技发展面上项目(No.KM201210011006)
北京市属高等学校科学技术与研究生教育创新工程建设项目~~
关键词
环糊精二聚体
主客体相互作用
超分子
功能材料
cyclodextrin dimer
host-guest interaction
supramolecular
functional materials
