摘要
A metal-organic coordination polymer [Ni（PDC）（bix）（H20）]n （H2PDC = 2,4-pyri- dinedicarboxylic acid, bix = 1,4-bis（imidazol-l-ylmethyl）-benzene） 1 has been hydrothermally synthesized and characterized by elemental analysis, IR, TG and single-crystal X-ray diffraction. Blue crystals crystallize in the monoclinic system, space group C2/c with a = 25.1475（18）, b = 13.1621（9）, c = 14.2739（10）A, β= 118.4150（10）°, V= 4155.4（5）A3, C21H19N5NiO5, Mr = 480.12, Dc = 1.535 g/cm3, F（000） = 1984, Z = 8, μ（MoKa） = 0.979 mm-1, the final R = 0.0478 and wR = 0.1004 for 3727 observed reflections （I 〉 2σ（I））. The structure of 1 exhibits a one-dimensional chain-like structure.
A metal-organic coordination polymer [Ni（PDC）（bix）（H20）]n （H2PDC = 2,4-pyri- dinedicarboxylic acid, bix = 1,4-bis（imidazol-l-ylmethyl）-benzene） 1 has been hydrothermally synthesized and characterized by elemental analysis, IR, TG and single-crystal X-ray diffraction. Blue crystals crystallize in the monoclinic system, space group C2/c with a = 25.1475（18）, b = 13.1621（9）, c = 14.2739（10）A, β= 118.4150（10）°, V= 4155.4（5）A3, C21H19N5NiO5, Mr = 480.12, Dc = 1.535 g/cm3, F（000） = 1984, Z = 8, μ（MoKa） = 0.979 mm-1, the final R = 0.0478 and wR = 0.1004 for 3727 observed reflections （I 〉 2σ（I））. The structure of 1 exhibits a one-dimensional chain-like structure.
基金
supported by the Science and Technology Research Projects of the Education Department of Jilin Province(No.2012.358)
