摘要
全面比较了薄层色谱法、气相色谱法、液相色谱法（HPLC）、气相色谱-质谱联用法（GC/MS）在禁用偶氮染料检测中的优缺点。分析实际检测中假阳性结果产生的原因，研究了8种致癌芳香胺的19种异构体在气相色谱和液相色谱上的分离情况，提出以GC/MS和HPLC互为确证手段的阳性结果鉴别方法，可有效提高定性结果的准确性，避免假阳性结果。
The advantages and disadvantages of thin layer chromatography, gas chromatography (GC), liquidchromatography(HPLC), GC/MS method in qualitaive analysis of 20 carcinogenic arylamines in prohibited azodyes were compared completely.The separation efficiency of 19 isomers of 8 carcinogenic arylamines wasstudied in GC and HPLC method. A new identification method of false positive result in the detection ofporhibited azo dyes was developed with cmmuting GC/MS and HPLC method. This method has been appliedsuccessfully to identify the true positive result and avoid the false positive result.
出处
《分析化学》
SCIE
EI
CAS
CSCD
北大核心
2000年第4期411-416,共6页
Chinese Journal of Analytical Chemistry
关键词
偶氮染料
致癌芳香胺
假阳性结果
鉴别
皮革
Azo dye, carcinogenic arylamine, false positive result, identification
