摘要
报道了一种新型可溶性聚N-(2-氯乙基)-2-氨基苯甲酰胺的化学合成,并用红外光谱、紫外-可见光谱、循环伏安法、X-射线衍射和溶解率测定对其结构与性能进行了研究。结果表明:这种聚苯胺衍生物没有共轭的醌式骨架,不具有电活性,可能是不导电的,呈现出非晶态结构,在乙醇、氯仿、DMF等普通有机溶剂中具有较好的溶解性。
In the paper,the chemical synthesis of novel soluble poly（N-（2-chloroethyl）-2-amino-benzamide） was reported and its structure and properties were studied by FTIR,UV-Vis,cyclic voltammetry,XRD and determination of solubility.The results suggested that the polyaniline derivative did not have conjugated quinoid backbone and electroactivity,was probably nonconducting,exhibited an amorphous structure,and had preferable solubility in common organic solvents like ethanol,chloroform and N,N-dimethyl formamide,etc.
出处
《广东化工》
CAS
2012年第9期77-79,共3页
Guangdong Chemical Industry
基金
西华师范大学科研启动经费项目(10B002)
关键词
聚苯胺
可溶性
聚合
电活性
polyaniline
soluble
polymerization
electroactivity
