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Ag_3PO_4/TiO_2纳米管阵列的制备及其可见光光催化活性 被引量：5

Fabrication and Visible-Light Photocatalytic Activity of Ag_3PO_4/TiO_2 Nanotube Arrays
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摘要 用浸渍-沉积法将Ag3PO4沉积在自组装TiO2纳米管阵列的管壁上制备Ag3PO4/TiO2纳米管阵列。用X射线衍射、扫描电子显微镜和紫外-可见漫反射光谱对样品进行表征。通过在可见光(λ>420nm)下降解水中的罗丹明B检测样品的光催化活性。结果表明:由于Ag3PO4与TiO2之间形成了异质结,在Ag3PO4的强可见光吸收性能和该异质结的协同作用下,Ag3PO4/TiO2异质结纳米管阵列的可见光光电催化活性高于单一的纯Ag3PO4和TiO2纳米管阵列膜。 Ag3PO4/TiO2 nanotube arrays were prepared via the deposition of Ag3PO4 on the tube wall of the self-organized TiO2 nanotube arrays by an impregnating-deposition method. The prepared samples were characterized by X-ray diffraction, scanning elec- tron microscope and ultraviolet visible absorption spectroscopy. The photocatalytic activity of the samples was evaluated by photo- catalytic degradation of rhodamine B aqueous solutions under visible-light irradiation （2 〉 420 nm）. The results show that AgaPO4/TiO2 nanotube arrays exhibit a higher photocatalytic activity rather than the respective pure AgaPO4 and TiO2 nanotube arrays due to the synergetic effects of two factors including the strong visible absorption of Ag3PO4 and the formation of heterojunction.
作者 刘素芹 梁英 刘华俊 罗天雄
机构地区 湖北文理学院化学工程与食品科学学院
出处 《硅酸盐学报》 EI CAS CSCD 北大核心 2012年第9期1242-1246,共5页 Journal of The Chinese Ceramic Society
基金 湖北省自然科学基金(No.2011CDA066 2008CDB014) 湖北省教育厅项目(No.Q20122507和Z20102601)资助
关键词 磷酸银 二氧化钛 纳米管阵列 光催化 可见光 siliver phosphate titanium dioxide nanotube arrays photocatalysis visible light
分类号 O643 [理学—物理化学]
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参考文献17

  • 1MACAK J M, ZLAMAL M, KRYSA J, et al. Self-organized TiO2 nanotube layers as highly efficient photocatalysts [J]. Small, 2007, 3(2): 300-304.
  • 2廖建军,李士普,曹献坤,曹阳,林仕伟.有序TiO_2纳米管阵列光催化性能研究进展[J].化工进展,2011,30(9):2003-2012. 被引量：12
  • 3LIU Z Y, PESIC B, RAJA K S, et al. Hydrogen generation under sunlight by self ordered TiO2 nanotube arrays [J]. lnt J Hydrogen Energy, 2009, 34(8): 3250-3257.
  • 4MOHAPATRA S K, MISRA M, MAHAJAN V K, et al. A novel method for the synthesis of titania nanotubes using sonoelectrochemical method and its application for photoelectrochemical splitting of water [J]. J Catal, 2007, 246(2): 362-369.
  • 5VARGHESE O K, PAULOSE M, GRIMES C A. Long vertically aligned titania nanotubes on transparent conducting oxide for highly efficient solar cells [J]. Nat Nanotechnol, 2009, 4(9): 592-597.
  • 6焦星剑,林红,李思钊,李建保.二氧化钛纳米管阵列制备及其在染料敏化太阳能电池中的应用[J].硅酸盐学报,2011,39(4):581-584. 被引量：8
  • 7HOFFMANN M R, MARTIN S T, CHOI W Y, et al. Environmental applications of semiconductor photocatalysis [J]. Chem Rev, 1995, 95(1): 69-96.
  • 8BERGER T, STERRER M, DIWALD O, et al. Light-induced charge separation in anatase TiO2 particles [J]. J Phys Chem B, 2005, 109(13): 6061-6068.
  • 9SUN W T, YU Y, PAN H Y, et al. CdS quantum dots sensitized TiO2 nanotube-array photoelectrodes [J]. J Am Chem Soc, 2008, 130(4): 1124-1125.
  • 10ZHANG H, QUAN X, CHEN S, et al. "Mulberry-like" CdSe nanoclusters anchored on TiO2 nanotube arrays: a novel architecture with remarkable photoelectrochemical performance [J]. Chem Mater, 2009, 21(14): 3090-3095.

二级参考文献73

  • 1O'REGAN B, GRATZEL M. A low-cost, high-efficiency solar-cell based on dye-sensitized colloidal TiO2 films [J]. Nature, 1991, 353: 737-740.
  • 2GRATZEL M. Perspectives for dye-sensitized nanocrystalline solar cells [J]. Prog Photovoltaics, 2000, 8(1): 171-185.
  • 3GONG D, GRIMES C A, VARGHESE O K, et al. Titanium oxide nanotube arrays prepared by anodic oxidation [J]. J Mater Res, 2001, 16: 3331-3334.
  • 4GRIMES C A. A review on highly ordered vertically oriented TiO2 nanotube arrays: Fabrication, material properties, and solar energy applications [J]. Sol Energy Mater Sol Cells, 2006, 90(14): 2011-2075.
  • 5XIE Z B, ADAMS S, BLACKWOOD D J, et al. The effects of anodization parameters on titania nanotube arrays and dye sensitized solar cells [J]. Nanoteclmology, 2008, 19: 405701.
  • 6KUANG D, BRILLET J, CHEN P, et al. Application of highly ordered TiO2 nanotube arrays in flexible dye-sensitized solar cells [J]. ACS Nano, 2008, 2(6): 1113-1116.
  • 7SHANKAR K, MOR G K, PRAKASAM H E, et al. Highly-ordered TiO2 nanotube arrays up to 220 Ima in length use in water photoeleetrolysis and dye-sensitized solar cells [J]. Nanotechnologty, 2007, 18: 065707.
  • 8VARGHESE O K, PAULOSE M, GRIMES C A. Long vertically aligned titania nanotubes on transparent conducting oxide for highly efficient solar cells [J]. Nat Nanotechnol, 2009(4): 592-597.
  • 9CHEN Q W, XU D S. Large-scale, noncurling, and free-standing crystallized TiO2 nanotube arrays for dye-sensitized solar cells [J]. J Phys Chem C, 2009, 113: 6310-6314.
  • 10JENN1NGS J R, GHICOV A, PETER L M, et al. Dye-sensitized solar cells based on oriented TiO2 nanotube arrays: transport, trapping, and transfer of electrons [J]. JAm Chem Soc, 2008, 130: 13364-13372.

共引文献17

同被引文献97

  • 1FUJISHIMA A, HONDA K. Electrochemical photolysis of water at a semiconductor electrode [J]. Nature, 1972, 238(7): 37-38.
  • 2ZHANG Huanjun, CHEN Guohua, BAHNEMANN Detlef W. Photoe- electrocatalytic materials for environmental applications [J]. J Mater Chem, 2009, 19(29): 509-5121.
  • 3CHEN Xiaobo, SHEN Shaohua, GUO Liejin, et al. Semiconductor- based photocatalytic hydrogen generation [J]. Chem Rev, 2010, 110(11): 6503-6570.
  • 4CHEN Xiaobo, MAO Samuel S. Titanium dioxide nanomaterials: synthesis, properties, modifications, and applications [J]. Chem Rev, 2007, 107(7): 2891-2959.
  • 5SU Chunyan, LIU Lei, ZHANG Mingyi, et al. Fabrication of Ag/TiO2 nanoheterostructures with visible light photocatalytic function via a solvothermal approach [J]. Cryst Eng Comm, 2012, 14(11): 3989- 3999.
  • 6QIAN Shasha, WANG Changsong, LIU Weijia, et al. An enhanced CdS/TiO2 photocatalyst with high stability and activity: effect of mesoporous substrate and bifunctional linking molecule [J]. J Mater Chem, 2011, 21(13): 4945-4952.
  • 7ZHANG Hao, ZONG Ruilong, ZHAO Jincai, et al. Dramatic visible photocatalytic degradation performances due to synergetic effect of TiO2 with PANI [J]. Environ Sci Technol, 2008, 42(10): 3803-3807.
  • 8YAN Hongjian, YANG Haoxin. TiO2-g-C3N4 composite materials for photocatalytic H2 evolution under visible light irradiation [J]. J Alloy Compd, 2011, 509(4): L26-L29.
  • 9YU Jiaguo, MA Tingting, LIU Shengwei. Enhanced photocatalytic activity of mesoporous TiO2 aggregates by embedding carbon nanotubes as electron-transfer channel [J]. Phys Chem Chem Phys, 2011, 13(8): 3491-3501.
  • 10ZHOU Wei, PAN Kai, QU Yang, et al. Photodegradation of organic contamination in wastewaters by bonding TiO2/single-walled carbon nanotube composites with enhanced photocatalytic activity [J]. Chemosphere, 2010, 81(5): 555-561.

引证文献5

二级引证文献24

硅酸盐学报
2012年 第9期

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