摘要
首先分析了乳液共聚合过程中出现的各种物理和化学变化 ,然后从以下几个方面回顾了各种不同的乳液共聚合数学模型 :乳胶粒形成 ,乳胶粒中自由基浓度 ,分子量分布和长链分支 ,单体在各相间的分配 ,速率常数的计算及竞聚率等 .
The physical and chemical changes in the emulsion copolymerizaton process were first analyzed m this paper,After this, a review on the development of mathematical model of emulsion copolymerization was performed with 52 referents. It included: particle nucleation, free radical concentration in the particle, molecular weight distribution and long chain branching monomer partitin between different phases,calculation of some kinetic constants,reactivity ratios,etc.
出处
《武汉化工学院学报》
2000年第3期35-39,共5页
Journal of Wuhan Institute of Chemical Technology
关键词
乳液共聚合
数学模型
综述
emulsion copolymerization
mathematical model
review
