期刊文献+

纳米结构多孔固体在二氧化碳吸附分离中的应用 被引量:6

Nanostructured porous solids for CO_2 sorption and separation
下载PDF
导出
摘要 二氧化碳(CO2)的双重角色(温室气体及一碳化工原料)使其吸附分离研究具有重要学术及社会经济意义。本文以多孔吸附材料为主线,系统评述了多孔炭、分子筛、有机金属骨架类材料及多孔聚合物等的CO2吸附分离最新研究进展。这些吸附材料的特点:多孔炭的微观及宏观形貌可控,孔结构可调,稳定性好;分子筛的具有丰富的微孔,孔径分布集中;有机金属骨架及多孔聚合物的种类多样,代表一类新兴的CO2吸附材料。分析了多孔固体应用于CO2吸附分离所涉及的关键科学问题,即高效吸附材料立体设计及影响选择性和吸附量等重要参数。提出澄清微孔/介孔/大孔比例以及表面基团种类和数量对CO2吸附贡献的定量关系的必要性,对材料的定向合成与优化有重要指导意义。 Due to the dual roles of CO2 as a main greenhouse gas and a renewable C1 carbon source,research on CO2 adsorption and separation is of great importance to both academic interests,and social and economic progresses.Based on various kinds of porous materials with distinct structural parameters,this paper reviews the recent development of novel porous CO2 sorbents and their sorption behavior.Porous carbons possess controllable micro/macroscopic morphology,tunable pore structure and good stability.Molecular sieves have rich microporosity with concentrated pore size distribution.Metal-organic frameworks and porous polymers offer a great variety of products,representing newly emerging CO2 capture materials.In addition,key issues on structure effect of new sorbents on high efficiency CO2 capture under actual conditions are discussed.Finally,perspectives on how to design the composite and the quantitative analysis of pore structure contributing to sorption capacity are provided.
出处 《化工进展》 EI CAS CSCD 北大核心 2012年第11期2493-2510,共18页 Chemical Industry and Engineering Progress
基金 教育部"新世纪优秀人才支持计划"(NCET-09-0254) 博士点基金(20100041110017) 中央高校基本科研业务费(DUT11ZD106) 教育部留学回国人员科研启动基金项目
关键词 多孔固体 吸附法 纳米结构 二氧化碳 吸附分离 porous solids adsorption process nanostructure carbon dioxide sorption and separation
  • 相关文献

参考文献136

  • 1Samanta A, Zhao A, Shimizu G K H, et al. Post-combustion CO2 capture using solid sorbents: A review[J]. Ind. Eng. Chem. Res., 2012, 51 (4): 1438-1463.
  • 2靳治良,钱玲,吕功煊.二氧化碳化学——现状及展望[J].化学进展,2010,22(6):1102-1115. 被引量:35
  • 3Song C. Global challenges and strategies for control, conversion and utilization of CO2 for sustainable development involving energy, catalysis, adsorption and chemical processing[J]. Catal. Today, 2006, 115 (1-4): 2-32.
  • 4Olah G A, Prakash G K S, Goeppert A. Anthropogenic chemical carbon cycle for a sustainable future[J]. J. Am. Chem. Soc., 2011, 133 (33): 12881-12898.
  • 5Martin C F, Stockel E, Clowes R, et al. Hypercrosslinked organic polymer networks as potential adsorbents for pre-combustion CO2 capture[J].J Mater Chem., 2011, 21 (14): 5475-5483.
  • 6Rao A B, Rubin E S. A technical, economic, and environmental assessment of amine-based CO2 capture technology for power plant greenhouse gas control[J]. Environ. Sci. Technol., 2002, 36 (20): 4467-4475.
  • 7Bollini P, Didas S A, Jones C W. Amine-oxide hybrid materials for acid gas separations[J].J. Mater Chem., 2011, 21(39): 15100-15120.
  • 8Bara J E, Camper D E, Gin D L, et al. Room-temperature ionic liquids and composite materials: Platform technologies for CO2 capture[J]. Acc. Chem. Res., 2010, 43 (1): 152-159.
  • 9Baker R W. Future directions of membrane gas separation technology[J], Ind. Eng. Chem. Res., 2006, 41 (6): 1393-1411.
  • 10Morris R E, Wheatley P S. Gas storage in nanoporous materials[J]. Angew. Chem. Int. Ed., 2008, 47 (27): 4966-4981.

二级参考文献49

  • 1程庆彦,钟顺和.二氧化碳和丙烯在Cu_2(OEt)_2/SiO_2催化下超临界合成甲基丙烯酸[J].化学通报,2004,67(7):517-523. 被引量:4
  • 2阴秀丽,常杰,汪俊锋,付严,吴创之,梁耀彰.生物质气化制甲醇的关键技术和可行性分析[J].煤炭转化,2004,27(3):17-22. 被引量:11
  • 3费维扬,艾宁,陈健.温室气体CO_2的捕集和分离——分离技术面临的挑战与机遇[J].化工进展,2005,24(1):1-4. 被引量:174
  • 4Xia K, Gao Q, Jiang J, et al. Hierarchical porous carbons with controlled micropores and mesopores for supercapacitor electrode materials [J]. Carbon, 2008, 46 : 1718-1726.
  • 5Li J, Wang X, Wang Y, et al. Structure and electrochemical properties of carbon aerogels synthesized at ambient temperatures as supercapacitors [J]. J Non-Cryst Solids, 2008, 354 : 19-24.
  • 6Xing W, Huang C C, Zhuo S P, et al. Hierarchical porous carbons with high performance for supercapacitor electrodes [J]. Carbon, 2009, 47 : 1715-1722.
  • 7Dou Y Q, Zhai Y, Liu H, et al. Syntheses of polyaniline/ordered mesoporous carbon composites with interpenetrating framework and their electrochemical capacitive performance in alkaline solution[J]. J Power Sources, 2011, 196: 1608-1614.
  • 8Chen Z, Qin Y, Weng D, et al. Design and synthesis of hierar- chical nanowire composites for electrochemical energy storage [ J ]. Adv Funct Mater, 2009, 19 : 3420-3426.
  • 9Huang C W, Wu Y T, Hu C C,. et al. Textural and electrochemical characterization of porous carbon nanofibers as elec- trodes for supercapacitors [J].J Power Sources, 2007, 172: 460-467.
  • 10Bao L, Zang J, Li X. Flexible Zn2SnO4/MnO2 core/shell nanocable-carbon microfiber hybrid composites for high-performance supercapacitor electrodes[J].Nano Lett, 2011, 11 : 1215-1220.

共引文献38

同被引文献68

引证文献6

二级引证文献30

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部