期刊文献+
任意字段
题名或关键词
题名
关键词
文摘
作者
第一作者
机构
刊名
分类号
参考文献
作者简介
基金资助
栏目信息

水溶性Pt(Ⅱ)-Salen配合物的合成、表征和光催化制氢研究 被引量：1

Synthesis,Characterization and Photocatalytic Hydrogen Production of Water-Soluble Pt(Ⅱ)-Salen Complex
下载PDF
导出
摘要 本文合成了一种水溶性的Pt(II)-Salen配合物(Salen=双5-磺酸钾水杨醛合邻苯二胺席夫碱),将其用于光催化制氢.研究发现在光催化制氢体系中仅存在Pt(II)-Salen配合物和三乙胺(TEA)而没有额外加入催化剂时,在可见光照射下有氢气产生.进一步的研究表明,Pt(II)-Salen配合物在体系中既是光敏剂,又是催化剂Pt纳米粒子的前体.同时,制氢体系中除了TEA外没有使用有机溶剂.该结果为简化多组分制氢体系提供了新思路. A new water-soluble Pt（Ⅱ）-Salen complex（Salen=NN′-substituted bis（salicyl-aldimine-5-sulphonic acid） potassium salt） was synthesized,characterized and employed in the photocatalytic hydrogen evolution system.In the presence of TEA,this system could produce hydrogen effectively without additional catalyst.An investigation found that the Pt（Ⅱ）-Salen complex could be employed as photosensitizer.Besides,it could also be the precursor of the catalyst.In addition,there was not organic solvent except TEA in the hydrogen evolution system.The result provided a new way to simplify the multi-component system for photocatalytic hydrogen production.
作者 樊仁杰 陈勇 傅文甫
机构地区 中国科学院理化技术研究所 中国科学院研究生院
出处 《影像科学与光化学》 CAS CSCD 北大核心 2012年第6期456-462,共7页 Imaging Science and Photochemistry
关键词 水溶性 铂配合物 SALEN配体 光催化制氢 water-soluble platinum（Ⅱ） complex Salen photocatalytic hydrogen production
分类号 O641.4 [理学—物理化学] TQ116.2 [化学工程—无机化工]
  • 相关文献

参考文献14

  • 1Hoffert M I, Caldeira K, Jain A K, Haites E F, Harvey L D D, Potter S D, Sehlesinger M E, Schneider S H, Watts R G, Wigley T M L, Wuebbles D J. Energy implications of future stabilization of atmospheric COz con- tent[J]. Nature,1998, 395(6705) : 881-884.
  • 2Lewis N S, Noeera D G. Powering the planet: chemical challenges in solar energy utilization[J]. Proc. Natl. Acad. Sci. USA, 2006, 103(43): 15729-35.
  • 3World Energy Assessment Report: Energyand the Challenge of Sustainability[M]. Program, U. N. D. , Ed. United Nations: New York, 2003.
  • 4Petit J R, Jouzl J, Raynaud D, Barkov N I, Barnola J M, Basile I, Bender M, Chappellaz J, Davis M, Delay- gue G, Delmotte M, Kotlyakov V M, Legrand M, Lipenkov V Y, Lorius C, Pepin L, Ritz C, Saltzman E, Stievenard M. Climate and atmospheric history of the past 420,000 years from the Vostok ice core, Antarctica [J]. Nature, 1999, 399(6735): 429-436.
  • 5Siegenthaler U, Stocker T F, Monnin E, L thi D, Schwander J, Stauffer B, Raynaud D, Barnola J-M, Fischer H, Masson-Delmotte V, Jouzel J. Stable carbon cycle climate relationship during the late pleistocene[J].Sci- ence, 2005, 310(5752): 1313-1317.
  • 6Esswein A J, Nocera D G. Hydrogen production by molecular photocatalysis[J]. Chem. Rev. , 2007, 107(10) 4022-4047.
  • 7何礼青,骆超,周前雄,侯原军,张宝文,王雪松.利用静电吸引作用提高光催化放氢效率[J].影像科学与光化学,2011,29(4):270-277. 被引量：2
  • 8Berry K J, Moya F, Murray K S, van den Bergen A M B, West B O. Wate-soluble cobalt(Ⅱ) complexes of NNP-substituted bis(salicylaldimine-5 sulphonic acids). Oxygen-carrying properties and conversion into cobalt (Ⅲ)organometallic compounds[J]. J. Chem. Soc., Dalton Trans., 1982, (1): 109-116.
  • 9Botsivali M, Evans D F, Missen P H, Upton M W. Studies on singlet oxygen in aqueous solution. Part 2. Wa- ter-soluble square-planar nickel complexes as quenchers[J].J. Chem. Soc. , Dalton Trans. , 1985, (6): 1147- 1149.
  • 10Botsivali M, Evans D F, Missen P H, Upton M W. Studies on singlet oxygen in aqueous solution. Part 2. Wa- ter-soluble square-planar nickel complexes as quenchers[J].J. Chem. Soc. , Dalton Trans. , 1985,(6): 1147- 1149.

二级参考文献11

  • 1Esswein M J, Nocera D G. Hydrogen production by molecular photocatalysis[J]. Chem. Rev. ,2007,107:4022- 4047.
  • 2Armaroli N, Balzani V. The future of energy supply: challenges and opportunities[J]. Angew. Chem. Int. Ed. , 2007, 46:52-66.
  • 3Walther D, Ruben D, Rau S. Carbon dioxide and metal centres: from reactions inspired by nature to reactions in compressed carbon dioxide as solvent[J]. Coord. Chem. Rev. ,1999, 182:67-100.
  • 4Wang M, Na Y, Gorlovb M, Sun L C. Light-driven hydrogen production catalysed by transition metal comple xes in homogeneous systems[J]. Dalton Trans. , 2009, 6458-6467.
  • 5Fihri A, Artero V, Pereira A, Fontecave M. Efficient H2-producing photocatalytic systems based on cyclometalated iridiumand tricarbonylrhenium-diimine photosensitizers and cobaloxime catalysts [J]. Dalton Trans., 2008,5567-5569.
  • 6Rau S, Schafer B, Gleich D, Anders E, Rudolph M, Friedrich M, Gorls H, Henry W, Johannes G. Vos. A supramoleeular photocatalyst for the production of hydrogen and the selective hydrogenation of tolane[J]. An gew. Chem. Int. Ed. ,2006, 45:6215-6218.
  • 7Lei P, Hedlund M, Lomoth R, Rensmo H, Johansson O, Hammarstrom L. The role of colloid formation in the photoinduced Hz production with a RuII-PdII supramolecular complex: a study by GC, XPS, and TEM[J]. J.Am. Chem. Soc. , 2008, 130: 26-27.
  • 8Goldsmith J l, Hudson W R, Lowry M S, Anderson T H, Bernhard S. Discovery and high-throughput screening of heteroleptic iridium complexes for photoinduced hydrogen production[J]. J. Am. Chem. Soc. , 2005, 127: 7502-7510.
  • 9Lowry M S, Hudson W R, Pascal R A, Jr. , Bernhard S. Accelerated luminophore discovery through combinatorial synthesis[J]. J. Am. Chem. Soc. , 2004, 126: 14129-14135.
  • 10Kellett R M, Spiro T G. Cobalt ( I ) porphyrin catalysis of hydrogen production from water[J]. Inorganic Chemistry,1985, 24: 2373-2377.

共引文献1

同被引文献9

引证文献1

二级引证文献1

影像科学与光化学
2012年 第6期

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部