摘要
Fluorescent microspheres of polystyrene-based Eu（Ⅲ） complexes were prepared from TentaGel resin, 2,6-bisbenzimidazolylpyridine and europium nitrate. The microspheres were characterized by FTIR spectroscopy, elemental analysis, XPS measurements and fluorescence spectroscopy. Characteristic red emission under irradiation of 365 nm light from a hand-held UV lamp was observed for the microspheres either in a solution or solid-state. Fluorescent quenching was observed when the microspheres were exposed to a trace amount of diethyl chlorophosphate （DCP） in the dispersion. The material and property can be potentially used to fabricate chemosensor in the detection of organophosphates.
Fluorescent microspheres of polystyrene-based Eu（Ⅲ） complexes were prepared from TentaGel resin, 2,6-bisbenzimidazolylpyridine and europium nitrate. The microspheres were characterized by FTIR spectroscopy, elemental analysis, XPS measurements and fluorescence spectroscopy. Characteristic red emission under irradiation of 365 nm light from a hand-held UV lamp was observed for the microspheres either in a solution or solid-state. Fluorescent quenching was observed when the microspheres were exposed to a trace amount of diethyl chlorophosphate （DCP） in the dispersion. The material and property can be potentially used to fabricate chemosensor in the detection of organophosphates.
基金
Project supported by Research Foundation of the General Armament Department (2008 CD 012)
