期刊文献+

粉末活性炭粒径对水中菲吸附动力学的影响效应研究 被引量:22

Effect of particle size on adsorption kinetics of phenanthrene in water by powered activated carbon
原文传递
导出
摘要 以菲为目标污染物,研究了粉末活性炭(PAC)在微尺度(1~100 μm)下的粒径效应对多环芳烃吸附性能的影响.实验中按照中值粒径将研磨后得到的粉末活性炭划分为:PAC-1(19 μm)、PAC-2(46 μm)、PAC-3(76 μm).通过比表面积及孔隙度自动分析仪、原位拉曼光谱、扫描电镜等手段对PAC物化性质进行表征,发现粒径减小使PAC的BET比表面积和总孔容增加了10%~20%左右,而对PAC表面化学性质的影响较小.PAC的粒径分布对其吸附性能有显著影响,这种影响主要体现为吸附速率成倍的增加,其次是吸附容量有30%~36%的增幅.分别用3种动力学模型对吸附过程进行拟合,结果表明,伪二级动力学方程的拟合程度最高,PAC-1有最大的吸附速率常数k,并且随着粒径的减小,k值逐渐增大. Taking phenanthrene as target pollutant, the effect of powered activated carbon (PAC) particle size in the range of 1 - 100 μm on adsorption kinetics of aqueous polycyclic aromatic hydrocarbons was investigated. PAC samples with different median particle diameters were obtained through grinding: PAC-1 (19 μm), PAC-2 (46 μm), and PAC-3 (76 μm). The physiochemical characteristics of original and three ground PACs were determined by surface area and porosity automatic analyzer, Raman spectroscopy and SEM-EDX, respectively. The results showed that with the decrease of particle size, surface area (BET) and micropore volume of PACs increased 10% - 20% , but no significant change on surface chemical properties was observed. Adsorption property differed markedly between three ground PACs, which was indicated by dramatic increase of adsorption rate and the significant increase of adsorption capacity with the decrease of particle diameter. Three kinetic equations were adopted to fit the kinetics data, and pseudo second-order equation matched the data best. PAC- 1 had the highest adsorption rate, and with the increase of particle size, the adsorption rate constant (k) decreased.
出处 《环境科学学报》 CAS CSCD 北大核心 2013年第1期67-72,共6页 Acta Scientiae Circumstantiae
基金 国家自然科学基金(No.50878204) 国家重点基础研究发展(973)计划(No.2011CB933704)~~
关键词 粉末活性炭(PAC) 吸附 粒径效应 动力学 powered activated carbon (PAC) adsorption particle size effect phenanthrene kinetics
  • 相关文献

参考文献26

  • 1Ando N, Matsui Y, Kurotobi R , et al. 2010. Comparison of natural organic matter adsorption capacities of super-powdered activated carbon and powdered activated Carbon [ J ]. Water Research, 44 (14) : 4127-4136.
  • 2Ando N, Matsui Y, Matsushita T, et al. 2011. Direct observation of solid-phase adsorbate concentration profile in powdered activated carbon particle to elucidate mechanism of high adsorption capacity on super-powdered activated carbon [ J ]. Water Research, 45 ( 2 ) : 761-767.
  • 3Barton S. 1986. The nature of the reaction between aqueous KOH and the acid surface oxides on porous carbons[J]. Colloid & Polymer Science, 264(2) : 176-181.
  • 4Chang C, Tsai W, lng C H, et al. 2003. Adsorption of polyethylene glycol (PEG) from aqueous solution onto hydrophobic zeolite[ J]. Journal of Colloid and Interface Science, 260(2) : 273-279.
  • 5Chen W, Duan L, Zhu D Q. 2007. Adsorption of polar and nonpolar organic chemicals to carbon nanotubes[ J]. Environmental Science & Technology, 41 (24) : 8295-8300.
  • 6Gai K,Shi B,Yan X M,et al. 2011. Effect of dispersion on adsorption of atrazine by aqueous suspensions of fullerenes [ J ]. Environmental Science & Technology, 45 (14) :5959-5965.
  • 7Guo X Y, Xiang D, Duan G H, etal. 2010. A review of mechanochemistry applications in waste management [ J ]. Waste Management, 30(1): 4-10.
  • 8Kannan N, Sundaram M M. 2001. Kinetics and mechanism of removal of methylene blue by adsorption on various carbons -- a comparative study[J]. Dyes and Pigments. 51 ( 1 ) : 25-40.
  • 9李士雨,王绍亭.不同粒径活性炭对中、小分子物质吸附平衡的差异与分析[J].生物医学工程学杂志,1996,13(1):5-9. 被引量:3
  • 10李艳,嵇阿琳.聚丙烯腈基炭纤维组织结构表征与性能分析[J].炭素技术,2010,29(1):5-9. 被引量:4

二级参考文献125

共引文献45

同被引文献351

引证文献22

二级引证文献172

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部