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聚醚型与聚酯型聚氨酯弹性体的性能研究 被引量:19

Study on Properties of Polyether and Polyester Polyurethane Elastomer
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摘要 使用聚乙二醇(PEG)、聚四亚甲基醚二醇(PTMG)、聚己内酯(PCL)和4,4'-二苯基甲烷二异氰酸酯(MDI)合成了聚醚多元醇型和聚酯多元醇型热塑性聚氨酯弹性体(TPU)。研究了各种TPU中异氰酸酯指数(R0)、硬段浓度(Ch)、聚醚和聚酯的种类、摩尔质量及原料用量等对弹性体力学性能的影响;并且使用双酚A型环氧树脂NPEL-127改性了弹性体的耐热性。研究结果表明:TPU的硬度随着R0和Ch的增加而增加;聚醚型TPU中,随着软段中柔性链的增加,TPU的硬度下降而力学性能提高;聚酯型TPU中,随着聚酯和聚酯二元醇摩尔质量的提高,TPU的硬度和力学性能均有提高;聚酯型TPU的力学性能优于聚醚型TPU;环氧树脂改性使得聚醚型TPU耐热性提高。 The thermoplastic polyurethane elastomer (TPU) was synthesized using polyether polyol of polyethylene glycol ( PEG ), poly ( tetramethylene ether) glycol ( PTMG ), polyester polyol polycaprolactone (PCL) and 4, 4' - diphenylmethane diisocyanate (MDI). The effect of isocyanate index (R0) , hard segment concentration (Ch) and type, molecular weight and amount of polyether polyol on the performance of polyurethane elastomer were studied. In addition, the bisphenol A epoxy resin NPEL-127 were used to modified the polyurethane elastomer in order to improve its heat resistance. The results showed that: the hardness of TPU increases with increasing Ro and Ch ; with the increase of molecular weight of the polyester and polyester diol, the hardness and mechanical properties of TPU was improved; the mechanical properties of polyester TPU was better than that of polyether TPU; the heat resistance of TPU modified by epoxy resin was improved.
出处 《塑料工业》 CAS CSCD 北大核心 2013年第2期87-89,114,共4页 China Plastics Industry
基金 陕西科技大学科研创新团队项目资助(TD10-01)
关键词 聚氨酯弹性体 聚酯型 聚醚型 改性 耐热性 Polyurethane Elastomer Polyester Polyether Modification Heat Resistance
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  • 1刘凉冰.聚氨酯弹性体的动态力学性能的影响因素[J].聚氨酯工业,2004,19(5):1-5. 被引量:19
  • 2翁汉元.聚氨酯胶黏剂概况和“十一五”发展规划建议[J].化学推进剂与高分子材料,2006,4(1):1-5. 被引量:4
  • 3乔吉超,胡小玲,管萍.聚氨酯胶粘剂的研究进展[J].热固性树脂,2006,21(5):44-48. 被引量:14
  • 4高家武,周福珍,刘士昕,等.高分子材料的热分析[M].北京:科学出版社,1990.
  • 5李英杰 杨惠昌 朱琰 等.聚氨酯热塑弹性体的热性能及动态力学性能.高分子材料科学与工程,1986,(1):39-44.
  • 6王源升 张宝真 姚树人.嵌段聚氨酯弹性体的动态力学性能研究.海军工程学院学报,1993,(3):35-38.
  • 7Ferguson J, Ahmad N. Chemical-structure and physical-properties in polyester based segmented polyurethanes: h dynamic mechanicalproperties [ J ]. European Polymer Journal, 1977,13 ( 11 ) :859 - 864.
  • 8Hartmann B, Duffy J V, Lee G F, et al. Thermal and dynamical mechanical properties of polyurethaneureas [ J ]. Journal of Applied Polymer Science, 1988,35 (7) : 1 829 - 1 852.
  • 9Sanders J H,Frisch K C.Polyurethanes.Interscience Publisher,1964.
  • 10Mutsuhisa F.Journal of Applied Polymer Science,1994:5361.

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