摘要
The modification of eutectic silicon is of general interest since fine eutectic silicon along with fine primary aluminum grains improves mechanical properties and ductilities. In this study, high intensity ultrasonic vibration was used to modify the complex microstructure of aluminum hypoeutectic alloys. The ultrasonic vibrator was placed at the bottom of a copper mold with molten aluminum. Hypoeutectic AI-Si alloy specimens with a unique in-depth profile of microstructure distribution were obtained. Polyhedral silicon particles, which should form in a hypereutectic alloy, were obtained in a hypoeutectic AI-Si alloy near the ultrasonic radiator where the silicon concentration was higher than the eutectic composition. The formation of hypereutectic silicon near the radiator surface indicates that high-intensity ultrasonic vibration can be used to influence the phase transformation process of metals and alloys. The size and morphology of both the silicon phase and the aluminum phase varies with increasing distance from the ultrasonic probe/radiator. Silicon morphology develops into three zones. Polyhedral primary silicon particles present in zone I, within 15 mm from the ultrasonic probe/radiator. Transition from hypereutectic silicon to eutectic silicon occurs in zone II about 15 to 20 pm from the ultrasonic probe/radiator. The bulk of the ingot is in zone III and is hypoeutectic AI-Si alloy containing fine lamellar and fibrous eutectic silicon. The grain size is about 15 to 25 IJm in zone I, 25 to 35 IJm in zone II, and 25 to 55 pm in zone II1. The morphology of the primary a-AI phase is also changed from dendritic （in untreated samples） to globular. Phase evolution during the solidification process of the alloy subjected to ultrasonic vibration is described.
The modification of eutectic silicon is of general interest since fine eutectic silicon along with fine primary aluminum grains improves mechanical properties and ductilities. In this study, high intensity ultrasonic vibration was used to modify the complex microstructure of aluminum hypoeutectic alloys. The ultrasonic vibrator was placed at the bottom of a copper mold with molten aluminum. Hypoeutectic Al-Si alloy specimens with a unique in-depth profile of microstructure distribution were obtained. Polyhedral silicon particles, which should form in a hypereutectic alloy, were obtained in a hypoeutectic Al-Si alloy near the ultrasonic radiator where the silicon concentration was higher than the eutectic composition. The formation of hypereutectic silicon near the radiator surface indicates that high-intensity ultrasonic vibration can be used to influence the phase transformation process of metals and alloys. The size and morphology of both the silicon phase and the aluminum phase varies with increasing distance from the ultrasonic probe/radiator. Silicon morphology develops into three zones. Polyhedral primary silicon particles present in zoneⅠ, within 15 mm from the ultrasonic probe/radiator. Transition from hypereutectic silicon to eutectic silicon occurs in zoneⅡ about 15 to 20 μm from the ultrasonic probe/radiator. The bulk of the ingot is in zoneⅢ and is hypoeutectic Al-Si alloy containing fine lamellar and fibrous eutectic silicon. The grain size is about 15 to 25 μm in zoneⅠ, 25 to 35 μm in zoneⅡ, and 25 to 55 μm in zoneⅢ. The morphology of the primary α-Al phase is also changed from dendritic (in untreated samples) to globular. Phase evolution during the solidification process of the alloy subjected to ultrasonic vibration is described.
基金
supported by the US Department of Energy,Office of Energy Efficiency and Renewable Energy,Industrial Technologies Program,Industrial Materials for the Future(IMF),under Contractor No.DE-PS07-02ID14270 with UT-Battelle,LLC
