摘要
A metal-organic framework （MOF） has been obtained by using a linker extension strategy. Three di-anions of 4-（3,5-dimethyl- 1H-pyrazol-4-yl）-benzoic acid coordinate to three Cu（I） ions forming an extended trigonal planar ligand, which links three di-copper paddlewheel units giving rise to a Pt304 net.
A metal-organic framework (MOF) has been obtained by using a linker extension strategy. Three di-anions of 4-(3,5-dimethyl- 1H-pyrazol-4-yl)-benzoic acid coordinate to three Cu(Ⅰ) ions forming an extended trigonal planar ligand, which links three di-copper paddlewheel units giving rise to a Pt3O4 net.
基金
supported by the U.S. Department of Energy (DOE Grants DE-FC36-07GO17033)
the Welch Foundation (A-1725)
supported by the National Science Foundation/Department of Energy under grant number NSF/CHE-0822838
supported by the U. S. Department of Energy, Office of Science, Office of Basic Energy Sciences, under Contract No. DE-AC02-06CH11357
