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4,4'-联吡啶类超分子化合物的合成、晶体结构及表征

Syntheses,Properties and Crystal Structures of the Supramolecula Compound Formed by 4,4'-bipyridine
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摘要 采用水热合成法,利用4,4'-联吡啶为桥联配体得到两种新型超分子化合物[(DPA)·0.5(4,4'-bipy)](1)和[Cd(H2O)2·(4,4'-bipy)2]2DSTA(2)(DPA=2,2'-联苯二甲酸、DSTA=2,2'-二硫代水杨酸),并通过X-射线单晶衍射分析、X-射线粉末衍射分析、元素分析和红外光谱对产物进行了表征。研究表明,化合物1通过O-H…N和C-H…O氢键构筑成2D的网络结构,化合物2中心镉离子为六配位构成1个八面体的配位结构,同时,化合物2中包含一个16.112×17.535(4,4)的2D拓扑结构。 Two new compounds, [ （DPA） ~ 0. 5（4,4＇-bipy） ] （1） and [Cd（H20）2 · （4,4＇-bipy）2] · 2DSTA（2）, have been synthesized with 4,4＇-bipyridine been hydrothermally synthesized [ DPA = 4,4 ＂-Biphenyldicarboxylie acid, DSTA =2,2＇-Dithiodibenzoie aeid and structural characteristic is obtained by elemental analysis, X-ray diffraction, IR spectroscopy and single-crystal X-ray diffraction. The structure of the compound 1 exhibits two-dimensional networks through O-HN and C-HO bonds. In compound 2, the Cd（II） ion is six-coordinated with a regular octahedral coordination geome- try. The research shows that this arrangement gives rise to a （4,4） connecting 2D topologie grid sheet with large rings of 16. 112 x 17. 535 A in diagonal distances.
作者 路璐 张宏伟 刘婷婷 袁菊 何林芯
机构地区 四川理工学院功能材料研究所 四川理工学院化学与制药工程学院
出处 《四川理工学院学报（自然科学版）》 CAS 2013年第2期15-19,共5页 Journal of Sichuan University of Science & Engineering(Natural Science Edition)
基金 四川理工学院基金项目(2011KY02) 四川理工学院大学生创新基金项目(CX20121304 CX20121309)
关键词 4 4’-联吡啶 晶体结构 水热合成 氢键 4,4＇-Bipy crystal structure hydrothermal synthesis Hydrogen bonding
分类号 O614.121 [理学—无机化学] O625.621 [理学—有机化学]
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参考文献20

  • 1Wang Jun,Wu Weiping,Lu Lu,et al. Self-assembly of wa- ter cluster in Cu(U)complexes and magnetic property[J]. Journal o f Molecular Structure,2013,1036 (27): 174 - 179.
  • 2Tong M L, Kitagawa S,Chang H C,et al. Temperature- controlled hydrotherrml synthesis of a 2D ferromaletic coordination bilayered polymer and a novel 3 D network with inorganic Co3(OH)2 ferrimagnetic chains[J].Chem Commun;2004(4):418-419.
  • 3Wang Jun,Lu Lu,Wu Weiping, et al. Synthesis and Crystal Structure of a New Coordination Polymer Constructed From Rigid Tetracarboxylate and N-Donor Ligands [J]. Synth React Inorg M2012,42(9):1217-1221.
  • 4Rosi N L, Eddaoudi M, Kim J, et al. lnfmite Secondary Building Units and Forbidden Catenation in Metal-Or- ganic Frameworks[J].Angew Chem Int Ed,2002,41 (2): 284-287.
  • 5Lam A W H,Wong W T,Gao S,et al.Synthesis,crystal structure,and photophysical and magnetic properties of dimeric and polymeric lanthanide complexes with benzoic acid and its derivatives[J].Eur J Inorg Chem,003,2003 (1):149-163.
  • 6Shi X, Zhu G S,Fang Q R, et al.Novel supramolecular frameworks self-assembled from one-dimensional poly- meric coordination chains [ J ]. Eur J Inorg Chem, 2004, 2004(1):185-191.
  • 7Huang F,Nagvekar D S,Sllebodnick C,et al.A supmmo- lecular triarm star polymer from a homotritopic tris (crown ether)host and a complementary monotopic pa- raquat-terminated polystyrene guest by a supmmolecular coupling method[J].J Am Chem Soc,2005,127(2):484- 485.
  • 8Shivaiah V,Das S K.Inclusion of a Cu2 Ion by a large- cavity crown ether dibenzo-24-crown-8 through supra- molecular interactions [ J]. Inorg Chem, 2005, 44 (21): 7313-7315.
  • 9Oh M,Carpen G B,Swei D A.Supramolecular metal-or- ganometallic coordination networks based on quinonoid complexes[J].Acc Chem Res2004,37(1):1-11.
  • 10Versteegen R M,Van Beek D,Sijbesma R P,et al.Den- drimer-based transient supramolecular networks [J]. J. Am Chem Soc2005,127(40):13862-13868.

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四川理工学院学报（自然科学版）
2013年 第2期

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