摘要
本文采用高温溶液法制备了PZN-PMN-PT晶体,利用X射线衍射仪(XRD)和扫描电子显微镜(SEM)分析了晶体的结构和微观形貌,通过偏光显微镜和介电温谱观测了晶体电畴和介电性能随温度的变化.研究结果表明,采用高温溶液法可以制备出纯钙钛矿相结构的PZN-PMN-PT晶体,晶体颗粒呈淡黄色多面体形态,最大尺寸为4mm×2.5mm×2mm,电畴的消光角为45°,三方四方相变温度达113℃,居里温度高达246℃.PZN-PMN-PT晶体的三方四方相变温度和居里温度均高于PZN-PT和PMN-PT晶体.
The PZN-PMN-PT ferroelectric crystal was prepared by the high temperature flux method. The structure and morphology were characterized by X-ray diffraction analysis （XRD） and scanning electron morphology （SEM）. The temperature dependence of domain and dielectric properties was performed by polarization microscope and impedance analyzer. It is indicated that the structure of PZN- PMN-PT crystal was confirmed with pure perovskite structure by the high temperature flux method. The largest size of PZN-PMN-PT crystal is 4mm×2.5mm×2MM. The extinction angle of domain was 45°. The higher Rhombohedral-tetragonal phase transition temperature and Curie temperature for PZN- PMN-PT crystal were found to be at 113 ℃ and 246 ℃ compared with that of PZN-PT and PMN-PT crystals, respectively.
出处
《西安工业大学学报》
CAS
2013年第2期134-139,共6页
Journal of Xi’an Technological University
基金
973计划项目(2013CB632904)
国家自然科学基金(51072155)
陕西省自然科学基础研究计划重点项目(2010JZ006)
关键词
PZN-PMN—PT晶体
高温溶液法
相结构
电畴
居里温度
PZN-PMN-PT single crystal
high temperature flux method
phase structure
domain
curie temperature
