摘要
研究了超声波(100 W,100 kHz)对电沉积Co-Ni合金层的结构、形貌和性能的影响。结果表明:施加超声波可有效降低电沉积过程中浓差扩散的影响,促进阴极表面与镀液界面间的电子转移。超声波可降低Co-Ni合金层的Co含量并细化晶粒,使Co-Ni合金层更为平整。超声波影响Co-Ni合金层结构和形貌,可提高Co-Ni合金层的硬度以及在3.5%NaCl溶液中的耐腐蚀性。
The effects of ultrasound agitation (100 W, 100 kHz) on the structure, morphology and prop- erties of electrodeposited Co-Ni alloy coatings were investigated in this paper. The result shows that: when ultrasonic agitation was used during the alloy coating electrodeposition, the concentration diffusion was effectively reduced, and the electron transfer between the cathode/solution interface was also pro- moted. Ultrasound agitation leads to the increase of Co content in alloy coating. The Co-Ni alloy coating deposited under ultrasound agitation is more fine-grained and uniform. The ultrasound agitation can lead to the enhancement of hardness and corrosion resistance properties of Co-Ni alloy coatings.
出处
《材料研究学报》
EI
CAS
CSCD
北大核心
2013年第3期267-272,共6页
Chinese Journal of Materials Research
基金
国家自然科学基金(51204115
50615024)
新世纪优秀人才支持计划(NCET-07-0536)资助项目~~
关键词
材料失效与保护
Co-Ni合金层
电沉积
静态
超声波
电化学
materials failure and protection, Co-Ni alloy coatings, electrodeposition, silent, ultra-sound, electrochemistry