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Two Fluorescent Complexes Assembled by Schiff Base 2-Methoxy-6-(phenyliminiomethyl) Phenolate Ligand

Two Fluorescent Complexes Assembled by Schiff Base 2-Methoxy-6-(phenyliminiomethyl) Phenolate Ligand
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摘要 Two d10 metal complexes Zn(NCS)2(C14HI3NO2)2 (1) and [Cd(NO3)2(CI4HI3NO2)2]. 4H20 (2) assembled by 2-methoxy-6-(phenyliminiomethyl) phenolate ligand (C14H13NO2, HL) have been synthesized and characterized by elemental analysis, IR and TG The single-crystal X-ray diffraction studies demonstrated that complex 1 crystallizes in monoclinic, P21/c space group with a = 17.321(7), b = 11.781(0), c = 15.593(2) A, fl = 110.273(6)°, V = 2984.95 A3, Z = 4, C30H26N404SzZn, Mr = 636.04, F(000) = 1312, Dc = 1.415 g/cm3,μ(MoKa) = 1.004 mm"1, the final R = 0.0403 and wR = 0.0900 for 21441 observed reflections with I 〉 20(/). Complex 2 is of monoclinic system, space group C2/c with a = 16.7767(2), b = 10.8989(2), c = 17.4928(2) A, fl = 90.614(9)°, V= 3198.37 A3, Z = 4, C28H34N4O14Cd, Mr= 731.25, F(000) = 1528, Dc = 1.568 g'cm^-3, μ(MoKa) = 0.757 mm-1, the final R = 0.0361 and wR = 0.0857 for 19811 observed reflections with I 〉 2σ(I). The two complexes were formed by Schiff base 2-methoxy-6-(phenyliminiomethyl) phenolate ligand and formed a 3D supramolecular architecture by π-πstacking interactions. Moreover, the complexes are luminescent in the solid state. These observations indicate that the complexes are promising system for the development of potential photoactive materials. Two d10 metal complexes Zn(NCS)2(C14HI3NO2)2 (1) and [Cd(NO3)2(CI4HI3NO2)2]. 4H20 (2) assembled by 2-methoxy-6-(phenyliminiomethyl) phenolate ligand (C14H13NO2, HL) have been synthesized and characterized by elemental analysis, IR and TG The single-crystal X-ray diffraction studies demonstrated that complex 1 crystallizes in monoclinic, P21/c space group with a = 17.321(7), b = 11.781(0), c = 15.593(2) A, fl = 110.273(6)°, V = 2984.95 A3, Z = 4, C30H26N404SzZn, Mr = 636.04, F(000) = 1312, Dc = 1.415 g/cm3,μ(MoKa) = 1.004 mm"1, the final R = 0.0403 and wR = 0.0900 for 21441 observed reflections with I 〉 20(/). Complex 2 is of monoclinic system, space group C2/c with a = 16.7767(2), b = 10.8989(2), c = 17.4928(2) A, fl = 90.614(9)°, V= 3198.37 A3, Z = 4, C28H34N4O14Cd, Mr= 731.25, F(000) = 1528, Dc = 1.568 g'cm^-3, μ(MoKa) = 0.757 mm-1, the final R = 0.0361 and wR = 0.0857 for 19811 observed reflections with I 〉 2σ(I). The two complexes were formed by Schiff base 2-methoxy-6-(phenyliminiomethyl) phenolate ligand and formed a 3D supramolecular architecture by π-πstacking interactions. Moreover, the complexes are luminescent in the solid state. These observations indicate that the complexes are promising system for the development of potential photoactive materials.
出处 《Chinese Journal of Structural Chemistry》 SCIE CAS CSCD 2013年第6期811-816,共6页 结构化学(英文)
基金 supported by the Natural Science Foundation of Zhejiang Province (LY12B01003)
关键词 d^10 metal complex 2-methoxy-6-(phenyliminiomethyl) phenolate ligand crystal structure luminescent d^10 metal complex, 2-methoxy-6-(phenyliminiomethyl) phenolate ligand, crystal structure, luminescent
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