摘要
基于经典密度泛函理论,研究了受限于球形空腔中的荷电硬球流体的分子缔合作用.计算和分析了外电场、荷电量和温度等因素对体系的平衡结构、剩余吸附和固-液界面张力的影响.所得结果可为研究其他复杂流体提供理论线索与参考.
Based on the classical density functional theory,the association of charged hard sphere fluid confined in spherical cavity is investigated.The influences of applied electrical field,charging,temperature on equilibrium structure,excess adsorption and solid-liquid interfacial tension are computed and analyzed.The results may provide useful theoretical clues and reference for investigation on other complex fluids.
出处
《河北师范大学学报（自然科学版）》
CAS
北大核心
2013年第4期359-363,共5页
Journal of Hebei Normal University：Natural Science
基金
河北农业大学非生命学科和新兴发展学科基金(FS200909)
华北电力大学校内基金(200911036)
关键词
荷电流体
密度泛函理论
缔合
剩余吸附
界面张力
charged fluids
density functional theory
association
excess adsorption
interfacial tension
