摘要简述了聚异戊二烯(IR)铁系、钛系、稀土、钼系等配位聚合催化剂研究进展。This perspective highlights recent research on the preparation of polyisoprenes employing well -characterized Fe, Co, RE and Mo complexes.
1Nogughi H , Kamkava S . New catalyst system for the polymerization of conjugated dienes [ J ] . J Polym Sci Polym Let, 1964,2(6) :5932 -596.
2Nakayma Y , Baba Y , Yasuda H , et al. Stereospecific polymerizations of conjugated dienes by single site iron complexes havingchelatingN, N, N - donorligands [ J ]. Macromolecules ,2003 ,36 : 7953 -7958.
3Ivanova I,Sushkevich V L,Kolyagin Y G,et al.Catalysis by coke deposits:synthesis of isoprene over solid catalysts[J].Angewandte Chemie,2013(125):13199-13202.
4Sushkevich V L,Ordomsky V V,Ivanova I I.Synthesis of isoprene from formaldehyde and isobutene over phosphate catalysts[J].Applied Catalysis A:General,2012(441/442):21-29.
5Dumitriu E,Hulea V,Fechete I,et al.Prins condensation of isobutylene and formaldehyde over Fe-silicates of MFI structure[J].Applied Catalysis A:General,1999(181):15-28.
