期刊文献+

多元多尺寸填料增强聚芳醚腈复合材料——聚芳醚腈/碳纤维/石墨烯微片复合材料

Multi-Scale Synergetic Reinforcement of PEN Composites by Carbon Fiber and Graphene Nanoplatelet
下载PDF
导出
摘要 报道了一种简单有效的增强热塑性塑料聚芳醚腈(PEN)力学性能的方法。该方法通过使用碳纤维(CF)和石墨烯微片(GN)实现多元多尺寸协同增强,通过熔融共混挤出造粒,得到力学性能优异的PEN/CF/GN复合材料。与PEN树脂、PEN/GN(5%)和PEN/CF(20%)复合材料相比,PEN/CF(20%)/GN(5%)复合材料的冲击强度分别增加了98.4%、63.6%、29.4%,其弯曲模量达到18.6GPa,分别增加了1.7、4.5、6.4倍。扫描电镜照片显示,微米尺寸CF和纳米填料GN的同时加入减少了基体富集区域和自由体积,增强了界面作用力,能够减少应力集中和帮助应力转移。同时加入CF和GN到聚合物系统中形成聚合物/微米/纳米体系,不仅具有显著的协同增强效应,能为材料设计提供参考,而且采用熔融注塑成型工艺,具有工业化生产前景。 An easy and efficient approach multi-scale carbon fiber (CF) and graphene to the development of advanced thermoplastic composites based on nanoplatelet (GN) reinforcement. Poly ( arylene ether nitrile ) (PEN) composites, prepared by the twin-screw extrusion, exhibited excellent mechanical properties. For example, the flexural modulus of PEN/CF/GN composites was 18.6 GPa, which was 1.7, 4.5 and 6. 4 times larger than those of PEN/CF composites, PEN/GN composites and PEN host, respectively. Based on the SEM image observation, such mechanical enhancements can be attributed to the synergetic effect of micro- scale CF and nano-scale GN in the PEN matrix (decreased matrix-rich and free-volume regions and enhanced interfacial interactions). This study had demonstrated that multi-scale CF and GN had an obvious synergetic reinforcing effect on the mechanical properties and thermal stabilities of thermoplastic composites, which provided an easy and effective way to design and improve the properties of composite materials.
出处 《塑料工业》 CAS CSCD 北大核心 2013年第S01期109-113,共5页 China Plastics Industry
关键词 聚芳醚腈 碳纤维 石墨烯微片 力学性能 协同增强 PEN Carbon Fiber Graphene Nanoplatelet Mechanical Properties Synergetic Reinforcement
  • 相关文献

参考文献22

  • 1TSANTZALIS S, KARAPAPPAS P, VAVOULIOTIS A, et al. On the improvement of toughness of CFRPs with resin doped with CNF and PZT particles [ J ]. Composites Part A, 2007, 38: 1159-1162.
  • 2JANG K, CHOW J, HA C S. Influence of processing method on the fracture toughness of thermoplastic-modified carbon-fiber-reinforced epoxy composites [ J ]. Compos Sci Technol, 1999, 59:995 - 1001.
  • 3DAVIES P, KAUSCH H H, WILIAMS J G, et al. Round- robin intertaminar fracture testing of carbon-fiber-reinforced epoxy and PEEK composites [ J ]. Compos Sci Technol, 1992, 43 : 129 - 136.
  • 4AN F, LU C X, LI Y H, et al. Preparation and character- ization of carbon nanotube-hybridized carbon fiber to reinforce epoxy composite [J]. Mater Des 2012, 33:197 -202.
  • 5JANG K, CHOW J, HA C S. Influence of processing method on the fracture toughness of thermoplastic-modified, carbon-fiber-reinforced epoxy composites [ J ]. Compos Sci Technol, 1999, 59:995-1001.
  • 6XUA Y, HOA S V. Mechanical properties of carbon fiber re- inforced epoxy/clay nanocomposites [ J ]. Compos Sci Tech- nol, 2008, 68: 854-861.
  • 7BEKYAROVA E, THOSTENSON E T, YU A, et al. Mul- tiseale carbon nanotube-carbon fiber reinforcement for ad- vanced epoxy composites [ J ]. Langmuir 2007, 23 : 3970 - 3974.
  • 8PARK R, JANG J. Performance improvement of carbon fi- ber/polyethylene fiber hybrid composites [ J ]. J Mater Sci, 1999, 34:2903-2910.
  • 9JANG J, YANG H. The effect of surface treatment on the performance improvement of carbon fiber/polybenzoxazine composites [ J]. J Mater Sci, 2000, 35 : 2297 -2303.
  • 10MARRAS S I, TSIMPLIARAKI A, ZUBURTIKUDIS I, et al. Morphological, thermal, and mechanical characteristics of polymer/layered silicate nanoeomposites : The role of fill- er modification level [ J]. Poly Eng Sci, 2009, 49 (6): 1206 - 1217.

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部