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凝胶渗透色谱净化-气相色谱法测定水产品中毒杀芬残留量 被引量:2

Determination of toxaphene residues in aquatic products by gel permeation chromatography and gas chromatography
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摘要 建立了水产品中毒杀芬残留量的凝胶渗透色谱净化-气相色谱检测方法。水产样品经匀浆后,用丙酮提取,经正己烷液液萃取、凝胶渗透色谱和浓硫酸净化后,用HP-5ms毛细管柱分离,电子捕获检测器检测,外标法定量。结果表明,毒杀芬在20~500μg/L浓度范围内线性良好,相关系数月≥0.998。方法检出限1.0μg/kg,在添加量2.0~20.0μgkg范围内,回收率在73.7%-78.7%之间,相对标准偏差≤6.3%。该方法灵敏、准确,可以满足水产品中毒杀芬检测要求。 A new method containing gel permeation chromatography (GPC) and gas chromatography with electron - capture detection ( GC - ECD) for the determination of toxaphene in aquatic products has been developed. After hom- ogenization, the samples were extracted by acetone, and then purified by liquid - liquid extraction. A further purifica- tion was conducted on a GPC system followed by a thorough clean - up with H2SO4. The separation was performed on an HP -5ms capillary column. Identification and quantification were conducted using GC -ECD. Toxaphene concen- tration exhibited a good linearity over the range of 20 -500 μg/L with R≥0.998. The detection limit of this method was 1.0 μg/kg for toxaphene. The recovery rates of toxaphene were 73.7% -78.7% at the range of 2.0 -20.0 μg/kg. This accurate and sensitive method can be applied for the determination of toxaphene residues in aquatic products.
出处 《中国渔业质量与标准》 2013年第3期73-77,共5页 Chinese Fishery Quality and Standards
基金 山东省现代农业产业技术体系刺参产业创新团队项目 国家海洋公益性行业科研专项(201105013) 山东省科学技术发展计划项目(2012GHY11517) 烟台市科技发展计划项目(2012134)
关键词 气相色谱 毒杀芬 水产品 残留 电子捕获检测器 gas chromatography ( GC ) toxaphene aquatic product residue electron capture detector(ECD)
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  • 1Kucklick J R, Helm P A. Advances in the environment alanalysis of olychlorinated naphthalenes and toxaphene [J]. Anal Bioanal Chem, 2006, 386(4) :819 -836.
  • 2Saleh M A. Toxaphene : Chemistry, biochemistry, toxici- ty, and environmental fate [ J ]. Rev Environ Contamin Toxicol, 1991, 118:1-85.
  • 3杨春,陈彬,陈敏,陈健,李渝萍,周长保,周度金,陈煊.毒杀芬对孤儿受体雌激素相关受体1(ERRα-1)的拮抗作用[J].第三军医大学学报,2001,23(10):1183-1185. 被引量:3
  • 4张兵,吴嘉嘉,刘国瑞,高丽荣,郑明辉.同位素稀释-气相色谱-串联质谱法测定土壤中的指示性毒杀芬[J].色谱,2010,28(5):456-459. 被引量:8
  • 5谢原利,饶竹,王晓华,王沫.加速溶剂萃取/气相色谱-负化学电离质谱法对土壤中毒杀芬的测定研究[J].分析测试学报,2009,28(7):804-808. 被引量:14
  • 6Veyrand B, Venisseau A, Marchand P, et al. Determina- tion of toxaphene specific congeners in fish liver oil and feedingstuff using gas chromatography coupled to high res- olution mass spectrometry [ J ]. J Chromatogr B, 2008, 865 : 121 - 126.
  • 7MacEachen D C, Cocks N. A GCMSD/ECD method for the simultaneous determination of toxaphene and toxa- phene congeners [J]. Chemosphere, 2002, 49:313 - 314.
  • 8石毓民.使用美国EPA方法大量快速分析土壤一油和水中POPS样品[C]//持久性有机污染物论坛2006暨第一届持久性有机污染物全国学术研讨会论文集.北京市:中国化学会,2006:124-128.
  • 9王明泰,刘志研,牟峻,李爱军.纺织品的毒杀芬残留量测定[J].印染,2006,32(6):37-40. 被引量:15
  • 10中华人民共和国国家质量监督检验检疫总局,中国国家标准化管理委员会.YC/T180-2004烟草及烟草制品.毒杀芬农药残留量的测定气相色谱法[S].北京:中国标准出版社,2004.

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