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有机硅保护剂在有机合成中的应用 被引量：3

The Applications of Organosilyl Protective Agents in Organic Synthesis
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摘要 介绍了有机硅保护剂的分类,特别是有机硅保护剂对结构中含羟基、羧基、羰基、端炔和氨基化合物的保护与脱保护的原理及应用情况,并对有机硅保护剂在高分子、有机合成和离子识别领域的应用分别做了简单综述. The paper introduced the classification of organosily protective agents, especially the principles and the applications of organosilyl protective agents for the protection of compounds containing hydroxy, carbonyl, mrboxyl, alkyne and amino-group. The applications of organosilyl protective agents in raacromolecule, organic synthesis and ion recognition were also covered.
作者 阮洋 彭丽亚 罗大鹏 刘海洪 章连众 倪勇 舒立金
机构地区 杭州师范大学有机硅化学及材料技术教育部重点实验室 浙江工业大学化学工程与材料学院
出处 《杭州师范大学学报（自然科学版）》 CAS 2013年第4期289-296,共8页 Journal of Hangzhou Normal University(Natural Science Edition)
基金 浙江省自然科学基金项目(LY12B04004) 杭州师范大学启动基金项目(2012ZX032)
关键词 有机硅保护剂 有机合成 高分子 离子识别 organosilyl protective agents organic synthesis macromolecule ion recognition
分类号 O627.41 [理学—有机化学]
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参考文献17

  • 1李英奇,彭雨春.三甲基氯硅烷在有机合成中的应用进展[J].精细化工中间体,2005,35(3):1-4. 被引量：7
  • 2Harding W W, Tidgewell K, Byrd N, et al. Neoclerodane diterpenes as a novel scaffold for μ opioid receptor ligands[J]. Journal of medicinal chemistry,2005,48(15) :4765-4771.
  • 3Yokomatsu T, Suemune K, Yamagishi T, et al. Highly. Regioselective silylation of a, β-dihydroxyphosphonates: an application to stereoselective synthesis of k,amino-β-hydroxyphosphoniC acid derivatives[J]. Synlett, 2000,1995 (8) : 847-849.
  • 4Wen Ke, Chow S, Sanghvi Y S, et al. Synthesis of 2'-O-methoxyethylguanosine using a novel silicon-based protecting group[J]. The Journal of Organic Chemistry, 2002,67 (22) : 7887-7889.
  • 5Bhatt R K, Chauhan K, Wheelan P, etal. 3-Hydroxyleukotriene B4 (3-OH-LTB4) : total synthesis and stereochemical assignment[J]. Journal of the American Chemical Society,1994,116(12) :5050-5056.
  • 6Kerr W J, Watson A J, Hayes D. In situ generation of Mes2Mg as a non-nucleophilic carbon-centred base reagent for the efficient one- pot conversion of ketones to silyl enol ethers[J]. Organic & Biomolecular Chemist:y,2008,6(7):1238-1243.
  • 7Srithanakit P, Chavasiri W. A new and efficient method for the synthesis of bromosilanes from hydrosilanes using Br3 CCOOEt/PdCI2 as the eatalyst[J]. Tetrahedron Letters,2011,52(19) :2505-2507.
  • 8Shu Lijin, Muri M, Krupke R, et al. Shape-persistent macrocycles comprising perfluorinated benzene subunits: synthesis, aggregation behaviour and unexpected mu-rod formation[J]. Org Biomol Chem,2009,7(6) :1081-1092.
  • 9Yamamoto Y. Silver-catalyzed Csp- H and Csp-Si bond transformations and related processes[J]. Chemical Reviews, 2008,108 (8):3199-3222.
  • 10Oberdorfer F, Zobeley A, Weber K, et al. Preparation of a-[3-11C] aminoisobutyric acid from an azadisilolidine derivative of alanine [J]. Journal of Labelled Compounds and Radiopharmaeeuticals, 1993,33(4):345-353.

二级参考文献15

  • 1Longhu,Zhou,Toshikazu Hirao. Vanadium-catalyzed stereoselective cyclodimerization of arylidene malononitrile in the presence of chlorosilane and zinc[J]. Tetrahedron Lett. 2000,41:8517～8521
  • 2M K Basu,F T Luo,Efficient transformation of nitrile into amide under mild condition[J]. Tetrahedron Lett. 1998,39: 3005～3006
  • 3F T Luo,A Jeevanandam. Simple transformation of nitrile into ester by the use of chlorotrimethylsilane [J ] . Tetrahedron Lett. 1998,39: 9455-9456.
  • 4Y Ishino, M Mihara, S Nishihama, etc. Zinc Metal-Promoted Stereoselective Olefination of Aldehydes and Ketones with gem-Dichloro Compounds in the Presence of Chlorotrimethylsilane [J] Bull. Chem. Soc. Jpn. , 1998,71:2669～2672
  • 5Y Horiguchi, S Matsuzawa, E Nakamura, I. Kuwajima, Me3 SiC1/HMPA accelerated conjugate addition of catalytic copper reagent. Stereoselective synthesis of enol silyl ether of aldehyde[J]. Tetrahedron Lett. 1986,27(34) :4025～4028
  • 6E Nakamura, S Matsuzawa, Y Horiguchi, etc. Me3SiCl accelerated conjugate addition of stoichiometric organocopper reagents[J]. Tetrahedron Lett. 1986,27(34) :4029～4032.
  • 7S I. Ikda,K Kondo,Y Sato. Nickel-Catalyzed Tandem Coupling of Enones, Alkynes, Alkynylzincs, and Chlorotrimethylsilane[J]. Chemistry Lett. 1999,11:1227～1228
  • 8K Afarinkia, H M. Binch,C Modi. Acceleration of nucleophilic addition to vinylphosphonates and vinyl phosphine oxides by chlorotrimethylsilane[J]. Tetrahedron Lett. 1998, 39:7419 ～7422.
  • 9J Eras,J J Mendez,M Balcells,etc. Chlorotrimethylsilane: A Suitable Reagent for the Synthesis of Chlorohydrin Esters[J].J. Org. Chem. 2002,67:8631～8634
  • 10S Bbaskaran, V Gpta, N Chidambaram, S Chandrasekaran. A facile conversion of alkenes to alcohols with benzyltriethylammonium borohydride chlorotrimethylsilane[J]. J. Chem. Soc. ,Chem. Commun. 1989,903

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杭州师范大学学报（自然科学版）
2013年 第4期

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