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Y_2SiO_5:Ce^(3+)/PMMA稀土发光复合材料的制备及其荧光性能的研究 被引量:2

Preparation and Luminescent Properties of Y_2SiO_5: Ce^(3+)/PMMA Composites
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摘要 采用原位聚合法,将蓝色荧光粉(Y2SiO5:Ce3+)和聚甲基丙烯酸甲酯(PMMA)复合,制备出透明且具有蓝色荧光性能的Y2SiO5:Ce3+/PMMA稀土发光复合材料。利用X射线衍射仪(XRD)和傅里叶红外吸收光谱仪(FT-IR)对样品进行结构分析;用扫描电镜(SEM)对样品进行微观形貌观察;用荧光光谱测试仪和紫外-近红外分光光度计对样品的荧光性能和透射光谱进行分析。结果表明:具有X2型单斜晶体结构的Y2SiO5:Ce3+蓝色荧光粉在PMMA中分布均匀,其粒度为0.7~2.0 m。在波长为365 nm紫外光激发下,Y2SiO5:Ce3+/PMMA复合材料能够发射出蓝色荧光,且0.1mol%Y2SiO5:Ce3+含量的PMMA基复合材料的蓝色荧光透光率高达75%。这表明所制备的Y2SiO5:Ce3+/PMMA复合材料具有良好的蓝色荧光性能,可用于透明固体发光器件的研制。 The Y2SiO5-Ce3+/PMMA composites were prepared by in-situ polymerization with blue photoluminescent powderY2SiO5-Ce3+and poly methyl methacrylate (PMMA) as starting materials. The obtained samples were characterized by XRD, FT-IR, SEM, etc. Results show that the Y2SiOs:Ce3+ luminescent powder with particle size of 0.7-2.0 μm has the X2-monoclinic crystal structure and is homogeneously distributed in the PMMA. Excited by the ultraviolet light with the wavelength of 365 nm, the Y2SiO5-Ce3+/PMMA composites exhibit the blue photoluminescence and the transparency of blue photoluminescence achieves a high value of 75%. Consequently, the obtained Y2SiO5-Ce3+/PMMA composites can be used to fabricate the transparent luminescent apparatus.
出处 《稀有金属材料与工程》 SCIE EI CAS CSCD 北大核心 2013年第9期1961-1964,共4页 Rare Metal Materials and Engineering
基金 国家自然科学基金(51071117) 西安市科技计划(CXY1015)
关键词 聚甲基丙烯酸甲酯(PMMA) Y2SiO5-Ce3+ PMMA复合材料 原位聚合法 蓝色荧光粉 透光率 Key words: poly methyl methacrylate Y2SiO5-Ce3+/PMMA composites in situ polymerization blue photoluminescence powder transparency
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