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Fe_3O_4@Cu_2O多孔纳米微球的制备及可见光光催化性能研究 被引量:1

Preparation of porous Fe_3O_4@Cu_2O nanocomposites and their photocatalytic activity under visible irradiation
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摘要 采用简单绿色的方法,在不加任何连接剂的情况下制备绒球状的多孔Fe3O4@Cu2O核壳纳米复合物.通过SEM、XRD、UV-Vis、BET以及精密SQUID磁学等手段对所制备产物的形貌、晶型、组成、比表面积以及磁性等进行分析.结果表明,这种结构新颖的多孔Fe3O4@Cu2O纳米复合物具有超顺磁性,在可见光下具有很好的光催化甲基橙(MO)降解的性能和循环稳定性,因此在环境净化方面具有潜在的应用价值. The Fe3O4@Cu2O nanocomposite microspheres were successfully synthesized by a facile, green route without any linkers. The morphology, crystallinity, composition, specific surface area and magnetism of the as-prepared composites were characterized by SEM, XRD, UV-Vis, BET, SQUID and so on. The results indicate that this novel porous Fe3O4@Cu2O nanocomposites are superparamagnetic and show efficient photocatalytic activity and high cycling stability while photocatalytic degradation of methyl orange (MO) under visible light irradiation. The composites will have potential applications in the environmental cleaning under sunlight.
出处 《安徽大学学报(自然科学版)》 CAS 北大核心 2013年第5期73-79,共7页 Journal of Anhui University(Natural Science Edition)
基金 国家自然科学基金资助项目(21171001 20731001)
关键词 Fe3O4@Cu2O 多孔材料 纳米微球 光催化 污染物降解 Fe3O4@Cu2O porous material microsphere photocatalysis degradation of pollutants
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  • 1Gogate P R, Pandit A B. A review of imperative technologies for wastewater treatment I: oxidation technologies at ambient conditions [ J ]. Advances in Environmental Research,2004,8 ( 3/4 ) : 501-555.
  • 2Malato S, Fernandez- Ibanez P, Maldonado M I, et al. Decontamination and disinfection of water by solar photocatalysis : recent overview and trends[ J]. Catalysis Today,2009,147 (1) :1-59.
  • 3Zhang Y Y, Chen J Z, Li X J. Preparation and photocatalytic performance of anatase/rutile mixed-phase TiO2 nanotubes [ J]. Catalysis Letters ,2010,139 (3/4) : 129-133.
  • 4Macak J M, Zlamal M, Krysa J, et al. Self-organized TiO2 nanotube layers as highly efficient photocatalysts [ J ]. Small, 2007,3 ( 2 ) : 300 - 304.
  • 5卢远刚,杨迎春,叶芝祥,刘盛余.氮掺杂Bi2O3光催化剂的制备及其可见光催化性能[J].无机材料学报,2012,27(6):643-648. 被引量:12
  • 6Kuo T J, Lin C N, Kuo C L, et al. Growth of uhralong ZnO nanowires on silicon substrates by vapor transport and their use as recyclable photocatalysts [ J ]. Chemistry of Materials ,2007,19 (21) :5143-5147.
  • 7章剑,章燕,沈玉华,李村,谢安建.花状结构Bi_2WO_6多孔微球:组装及光催化性能[J].无机化学学报,2012,28(4):739-744. 被引量:12
  • 8Yang F, Takahashi Y, Sakai N, et al. Photocatalytic remote oxidation induced by visible light [ J ]. Journal of Physical Chemistry C, 2011,115 ( 37 ) : 18270-18274.
  • 9Chen C, Ding G J, Zhang D, et al. Microstructure evolution and advanced performance of Mn3 04 nanomorphologies [ J ]. Nanoscale,2012,4 ( 8 ) :2590-2596.
  • 10方林霞,王玲玲,余萌,井强山.制备方法对Ti_(0.8)Zr_(0.2)O_2/沸石结构及光催化性能的影响[J].信阳师范学院学报(自然科学版),2012,25(4):508-511. 被引量:4

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  • 1MOHAN D, SINGH K P.Single and multi-component adsorption of cadmium and zinc using activated carbon derived from bagasse-an agricultural waste [ J ]. Water Research, 2002,36 (9) : 2304-2318.
  • 2SONG Xuefeng, GAO Lian.Fabrication of bifunctional titania/silica - coated magnetic spheres and their photocatalytic activ- ities[J]. Journal of the American Ceramic Society,2007,90(12):4015-4019.
  • 3GUO Shaojun, DONG Shaojun, WANG Erkang. A general route to construct diverse multifunctional Fe3OJmetal hybrid nanostructures [ J ]. Chemistry - A European Journal, 2009,15 (10) : 2416-2424.
  • 4WANG Leyu, BAI Jingwei, LI Yujing, et a/.Muhifunctional nanoparticles displaying magnetization and near-IR absorption [ J ]. Angewandte Chemie International Edition, 2008,47 (13) : 2439-2442.
  • 5LOU X W, YUAN C, RHOADES E, et a/.Encapsulation and ostwald ripening of Au and Au - C1 complex nanostructures in silica shells [ J ]. Advanced Functional Materials, 2006, 16 ( 13 ) : 1679-1684.
  • 6LO C K,XIAO D,CHOI M M F.Homocysteine-protected gold-coated magnetic nanoparticlcs :synthesis and characterization [J ]. Journal of Materials Chemistry, 2007,17 : 2418-2427.
  • 7WANG Lingyan, LUO Jin, MAYE M M, et a/.Iron oxide - gold core - shell nanoparticles and thin film assembly [J]. Jour- nal of Materials Chemistry,2005,15 : 1821-1832.
  • 8LI Shikuo, HUANG Fangzhi, WANG Yang, et M.Magnetic Fe304@C@CuO composites with bean-like core/shell nanostruc- tures:Synthesis,properties and application in recyclable photocatalytic degradation of dye pollutants [J]. Journal of Mate- rials Chemistry, 2011,21 : 7459-7466.
  • 9KUO C H, HUA T E, HUANG M H.Au nanocrystal-directed growth of Au-Cu20 core-shell heterostructures with pre- cise morphological control[J]. Journal of the American Chemical Society,2009,131 (49):17871-17878.
  • 10KUO C H, CHEN C H, HUANG M H.Seed-mediated synthesis of monodispersed Cu20 nanocubes with five different size ranges from 40 to 420 nm[J ]. Advanced Functional Materials, 2007,17( 18):3773-3780.

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