摘要
岩浆型铁矿床是我国的重要铁矿类型之一,也是峨眉山地幔柱系统的有机组成部分。但是,这类矿床的成因问题长期没有解决。本文以黑山铁矿中的脉状矿体为例,试图通过锆石矿物地球化学的系统分析揭示岩浆型铁矿床脉状铁矿体的成因。锆石Ti温度计和δCe氧逸度计计算结果表明,脉状铁矿体的成矿温度T介于631~768℃之间,加权平均为681℃;成矿氧逸度logf O2介于-25.7^-15.6之间,加权平均为-20.8。这与实验得到的富铁质岩浆成矿温度相差近400℃,但又明显高于岩浆热液的温度。因此,本文认为"铁矿浆"很可能是溶解了大量成矿金属的超临界流体,处于岩浆-热液过渡状态。这一认识得到了锆石(Sm/La)N vs.La和Ce/Ce*vs.(Sm/La)N判别图解,以及CL图像的进一步支持。大量流体组分的存在能够有效降低"铁矿浆"的粘度和密度,从而有利于其沿裂隙贯入或挤入围岩中,这可以很好的解释铁矿体的不规则脉状产状和围岩蚀变特征。结合前人资料,"铁矿浆"中的流体组分包括C-H-O-S等,这些流体组分除了岩浆自身结晶分异作用而富集的挥发分外,还包括外来幔源流体和地表流体的加入。"铁矿浆"在贯入围岩后经历了相分离作用,因而触发了钛铁氧化物的结晶从而富集形成矿石,这一流体地质过程记录在锆石Eu异常特征中。黑山铁矿床脉状铁矿体的形成机理可能也适用于包括攀枝花式铁矿在内的其他岩浆型铁矿床中的脉状铁矿体。
Magmatic iron deposit is not only one of the most important typies of iron resources in China, but also an intimate component of the Emeishan mantle plume. However, the metallogenic mechanism of magmatic iron deposit is still controversial. We investigate the vein-type iron orebody in the Heishan iron deposit as an example, and aim to unravel the genesis of vein-type iron orebody in magmatic iron deposit by zircon mineral geochemistry. Using Ti-in-zircon geothermometer and δCe-in-zircon oxygen geobarometer, the metallogenic temperature and oxygen fugacity of vein-type iron orebody are 631 ～768℃ （average = 681℃ ） and - 25. 7 ～- 15.6 （ average = - 20. 8）, respectively. It is much lower than the saturation of ferro-rich magma about 400℃, and higher than the temperature of hydrothermal fluid, which imply the ＂iron ore magma＂ is in the state of supercritical fluid dissolving numerous metal material. This conclusion is further confirmed by the CL images, discriminant diagrams of （Sm/La）N vs. La and Ce/Ce＊ vs. （Sm/La） N for zircons. Being enriched with fluid component would effectively reduce the viscosity and density of ＂iron ore magma＂ and be beneficial to its injection, which could well interpret its irregular-shaped vein occurrence and wall-rock alteration. Based on previous studies, chemical components of the fluid component in the ＂iron ore magma＂ comprise C-H-O-S, which are enriched by magma fractional crystallization and addition of transmagmatic and surface fluid. Phase separation after injection of the ＂iron ore magma＂ triggers crystallization of Fe-Ti oxide and ore-formation. This fluid geological process is recorded by Eu anormaly in zircon. The metallogenic mechanism of the vein-type iron orebody in the Heishan iron deposit may be comparable to that of other magmatic iron deposits, including the Panzhihua-type iron deposits.
出处
《岩石学报》
SCIE
EI
CAS
CSCD
北大核心
2013年第10期3555-3566,共12页
Acta Petrologica Sinica
基金
国家重点基础研究发展计划(973)项目(2011CB808901)
中国地质调查局地质调查项目(1212011220921
12120113094100)联合资助
关键词
岩浆型铁矿床
矿浆
黑山
超临界流体
锆石Ti温度计
锆石δCe氧逸度计
攀枝花式铁矿
Magmatic iron deposit
Ore magma
Heishan
Supercritical fluid
Ti-in-zircon geothermometer
δCe-in-zircon oxygengeobarometer
Panzhihua-type iron deposit
