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混煤燃烧过程中矿物质的形态变化及相变 被引量:14

CONFORMATION CHANGE AND PHASE TRANSFORMATION OF MINERALS DURING COAL BLENDS COMBUSTION
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摘要 In this paper,the ash fusion characteristics and mineral behavior of individual coal ash and a series of two-component blendsd ashes are studied.The samples are heated progressively from(IT)at 100?℃intervals in reducing atmosphere.Mineral composition and type at each temperature interval are determined by X-ray diffraction (XRD)analysis.For different coal ashes,the main mineral matter at 800?℃is quartz,anhydrite and hematite,calcite and feldspar.With increasing temperature,oxidation,thermal decomposition,transformation and reaction occur between the components.It can be seen that quartz,anhydrite decrease and anorthite,gehlenite increase.At about 1200?℃,all of mineral diminish and a glass phase is formed.Some combinations of mineral in component coal produce low-melting eutectic composition at a high temperature and this is the main reason causing the non-arithmetic average of softening temperature of blends ash. In this paper,the ash fusion characteristics and mineral behavior of individual coal ash and a series of two-component blendsd ashes are studied.The samples are heated progressively from(IT)at 100?℃intervals in reducing atmosphere.Mineral composition and type at each temperature interval are determined by X-ray diffraction (XRD)analysis.For different coal ashes,the main mineral matter at 800?℃is quartz,anhydrite and hematite,calcite and feldspar.With increasing temperature,oxidation,thermal decomposition,transformation and reaction occur between the components.It can be seen that quartz,anhydrite decrease and anorthite,gehlenite increase.At about 1200?℃,all of mineral diminish and a glass phase is formed.Some combinations of mineral in component coal produce low-melting eutectic composition at a high temperature and this is the main reason causing the non-arithmetic average of softening temperature of blends ash.
出处 《化工学报》 EI CAS CSCD 北大核心 2000年第6期840-843,共4页 CIESC Journal
基金 国家自然科学基金!资助项目 (No.5 9876 0 12 )
关键词 矿物质 形态变化 相变 混煤 燃烧 结渣机理 blended coal ash,mineral,conformation change,phase transformatip
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参考文献1

  • 1Qiu Jianrong,International Conferenceon Power Engineering,1997年,465页

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