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红外透过、反射吸收光谱研究手性液晶(M_1)LB膜的结构与取向 被引量:3

Infrared Study on Molecular Structure and Orientation in Langmuir-Blodgett Films of Chiral LCs M_1
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摘要 利用FTIR光谱研究了一种手性液晶化合物 (M1)LB膜的结构与取向 ,该化合物可以形成稳定的单层与多层膜。手性分子中 ,芳香环平面部分倾向于垂直基片表面 ,分子中的烷基链部分则与基底表面法线方向成一定的角度。 The LB films of chiral LCs M 1 were investigated by FTIR transmission and reflection absorption spectra.CaF 2 and vacuum deposition gold plate were used as solid substrate.The LB films can be transferred onto the solid substrate successfully.The orientation of LB films was analysis by comparing the FTIR transmission and reflection absorbance spectroscopy.The aromatic cores part which including the C—O bond was almost perpendicular the substrate surface,the alkyl chain and C=O part has a certain angle titled onto the substrate.
出处 《光谱学与光谱分析》 SCIE EI CAS CSCD 北大核心 2000年第6期768-769,共2页 Spectroscopy and Spectral Analysis
基金 国家自然科学基金!重点项目 (96330 1 0 )资助课题
关键词 手性液晶体合物(M1) LB膜 取向 结构 红外光谱 Chiral LCs(M 1), LB films, Orientation
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参考文献5

  • 1N A Clark and S T Lagerwall. J. Applied Physics Letters . 1980
  • 2H Furure,Y Iimuka,Y Miyamoto and H Endoh. Japanese Journal of Applied Physics . 1998
  • 3R Azumi,M Matsumoto,S Kuroda and M Crossley. Langmuir . 1995
  • 4T Hasegawa,S Takeda,A Kawaguchi and J Umemura. Langmuir . 1995
  • 5T Kawai,J Umemura and T Takenka. Langmuir . 1990

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