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云杉红翅小蠹信息素Seudenone和(±)-Seudenol的简便合成 被引量:1

A Facile Synthesis of Seudenone and Racemic Seudenol
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摘要 3-甲基环己 - 2 -烯 - 1 -酮 (Seudenone)是云杉红翅小蠹的抑制信息素 ,3-甲基环己 - 2 -烯- 1 -醇 (± -Seudenol)却是一种聚集信息素 .本合成利用乙酰乙酸乙酯和多聚甲醛为原料 ,通过缩合。 Seudenone (3-methylcyclohex-2-en-1-one) is an antiaggregation pheromone of Douglas fir beetle, Dendroctonus pseudotsugae.Seudenol (3-methyl cyclohex-2-en-1-ol) is an aggregation pheromone of Douglas fir beetle, Dendroctonus pseudotsugae .The synthesis employed ethyl acetoacetate and paraformaldehyde as starting materials.The route of synthesis was carried out by 3 steps:condensation,hydrolysis and decaxboxylation,and regioselective reduction.
出处 《云南大学学报(自然科学版)》 CAS CSCD 2000年第6期443-445,共3页 Journal of Yunnan University(Natural Sciences Edition)
基金 The Applied Basic Research Foundation of Yunnan Province China(98C017M)
关键词 3-甲基环己-2-烯-1-酮 3-甲基环己-2-烯-1-醇 信息素 合成 seudenone Seudenol pheromone synthesis
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同被引文献18

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  • 2王莹,杨秀伟.不同炮制品怀小白菊挥发油成分的GC-MS分析[J].中国中药杂志,2006,31(6):456-459. 被引量:21
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