摘要
3-甲基环己 - 2 -烯 - 1 -酮 (Seudenone)是云杉红翅小蠹的抑制信息素 ,3-甲基环己 - 2 -烯- 1 -醇 (± -Seudenol)却是一种聚集信息素 .本合成利用乙酰乙酸乙酯和多聚甲醛为原料 ,通过缩合。
Seudenone (3-methylcyclohex-2-en-1-one) is an antiaggregation pheromone of Douglas fir beetle, Dendroctonus pseudotsugae.Seudenol (3-methyl cyclohex-2-en-1-ol) is an aggregation pheromone of Douglas fir beetle, Dendroctonus pseudotsugae .The synthesis employed ethyl acetoacetate and paraformaldehyde as starting materials.The route of synthesis was carried out by 3 steps:condensation,hydrolysis and decaxboxylation,and regioselective reduction.
出处
《云南大学学报(自然科学版)》
CAS
CSCD
2000年第6期443-445,共3页
Journal of Yunnan University(Natural Sciences Edition)
基金
The Applied Basic Research Foundation of Yunnan Province China(98C017M)