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聚合物表面金属化改性的研究进展 被引量:1

Progress of Surface Modification for Surface Metallization of Polymers
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摘要 表面金属化的聚合物因其卓越的综合性能广泛应用于多个领域,但聚合物表面金属化过程中通常会出现金属薄膜与基底材料附着力较差的问题,限制了其实际应用。为解决这一问题,多种表面改性技术被用来对聚合物的表面性质进行修饰。文中探讨了聚合物上金属薄膜附着力较差的原因并介绍了目前用以改善薄膜附着力的聚合物表面改性技术的研究进展,比较了离子注入、等离子体处理、离子束辐照、化学法、光化学法及准分子激光刻蚀等不同技术的改性效果和改性机理,对工业化应用需要克服的问题和研究方向也作了展望。 Surface metallized polymers were widely used in many fields due to their excellent properties. Since the adhesion of metal film to the base polymer is usually poor, their practical applications was limited. In order to solve this problem, several surface modification techniques were employed to modify the surface properties of polymer. The reason of adhesion weakness was analyzed. The progress of polymer surface modification techniques, such as ion implantation, plasma treatment, ion beam ,irradiation, chemistry, photo-chemistry and excimer laser etching was reviewed. The modification effects and mechanisms of these techniques were alto compared. At last, the direction and problems of industrial application were prospected on the basis of current research status.
出处 《高分子材料科学与工程》 EI CAS CSCD 北大核心 2013年第11期187-190,共4页 Polymer Materials Science & Engineering
基金 国家自然科学基金资助项目(51076032) 广东省教育部产学研结合项目(2012B091100296)
关键词 聚合物 表面金属化 附着力 表面改性 工业化应用 polymer surface metallization adhesion surface modification industrial application
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参考文献21

  • 1Xu W, Yang J S, Lu T J. Ductility of thin copper films on rough poiymer substrates[ j J. Materials and Design, 2011, 32 ( 1 ) : 154- 161.
  • 2Kinl W S, Yun 1 H, Lee J J, et al. Evaluation of mechanical interlock effect on adhesion strength of polynmr-metal interfaces using micro-patterned surface topography [ J ]. lnt. J. Adhes. Adhes, , 2010, 30(6):408-417.
  • 3Kisin S, Scahro F, Malanowski P, et al. Chemical and structural changes at the ABS polymer-copper metal interface [ J ]. Polym. Degrad. Stab., 2007, 92(4): 605-610.
  • 4高原,邢安,殷军港,秦晓刚,刘惠涛.高分子基材料表面改性研究进展[J].高分子材料科学与工程,2012,28(6):172-175. 被引量:5
  • 5Lee S W, Hong J W, Wye M Y, et al. Surface modification and adhesion improvement of PTFE film by ion beam irradiation [ J ]. Nucl. instrum. Methods Phy. Res. B, 2004, 219-220; 963-967.
  • 6Kim S H, Na S W, Lee N E, et al. Effect of surface roughness on the adhesion properties of Cu/Cr fihns of polyimide substrate treated by inductively coupled oxygen plasma [ J ]. Surf. Coat. Tcchnol. , 2005, 200(7): 2072-2079.
  • 7Sanchis M R, Blancs V, Blanes M, et al. Surface modification of low density polyethylene (LDPE) film by low pressure 02 plasma treatment[J]. Eur. Polym. J, 2006, 42(7): 1558-1568.
  • 8jung C H, Cho H W, Hwang I T, et al. The effects of energetic ioa irradiation on metal-to-polymer adhesion[J]. Radiat. Phys. Chem., 2012, 81(8): 919-922.
  • 9Chaiwong C, Mckenzie 13 R, Bilek M M M, et ,J. Siudy of adhesion of TiN grown on a polymer substrate[J]. Surf. Com. Technol. , 2007. 201(15) : 6742-6744.
  • 10Pundt A0 Nikitin E, Pekarski P, et al. Adhesion energy betwcea metal films and polymers ob*ained by studying buckling induced by hydrogenlJ]. Acta Materialia, 2004, 52(6): t579-1587.

二级参考文献48

  • 1陆静娟,郭兴忠,杨辉.有机/无机复合透明耐磨薄膜的制备[J].高分子材料科学与工程,2006,22(1):211-214. 被引量:21
  • 2[1]Raymond L B,Goldsmith S. Principles and application of vacuum arc[J]. IEEE Trans Plasma Science, 1989,17(5) :705-798.
  • 3[2]Meassick S,Chan C, Allen R. Thin film deposition techniques utilizing the anodic vacuum arc[J]. Surf Coat Technol, 1992,54-55:343-348.
  • 4[3]Anders S, Anders A,Brown I G. Transport of vacuum arc plasmas through magnetic macro-particle filters[J].J Appl, Phys, 1993.74: 4239.
  • 5[4]Zhang Huixing,Zhang Xia oji. Research in and industrial application of metal source ion implantation at Beijing Normal University[J]. Surf Coat Technol, 1998,103-104: 200-204.
  • 6[5]Jackson S T,Nuzzo R G. Determining hybridization differences for amorphous carbon from the XPS C ls envelope[J]. Appl Surf Sci, 1995,90(2): 195-203
  • 7[1]Lee E H, Rao G R, Lewis M B, et al. Ion implantation application for improved polymer surface properties. Nucl Instr Meth, 1993, B74: 326~330
  • 8[2]Wang Y Q, Mohite S S, Bridwell L B. Modification of high temperature and high performance polymer by ion implantation. J Mater Res, 1993, 8(2): 388~401
  • 9[3]Popok V N, Karpovich I A, Odzhaev V B, et al. Structure evolution of implanted polymer: Buried conductive layer formation. Nucl Instr Meth, 1999, B148: 1106~1 110
  • 10[4]Lee E H. Ion beam modification of polymeric materials-fundamental principles. Nucl Instr Meth, 1999, B151: 29~41

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