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高纯度松木纤维素提取工艺研究 被引量:3

Study on extraction of high purity pine cellulose
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摘要 以松木屑为原料,提取了高纯度的松木纤维素。采用2次碱化、1次酸化的方法,研究了碱化和酸化过程中各因素对松木纤维素纯度的影响,对提取的高纯度松木纤维素进行硝酸乙醇纤维素和α-纤维素含量测试,并用FT-IR和XRD进行分析。得到松木纤维素提取最佳工艺:首先碱处理NaOH质量分数为6%,温度为100℃(反应固液比为1g∶15 mL,处理时间为120 min);然后碱处理NaOH质量分数为12%,固液比为1 g∶40 mL,固定处理温度为100℃处理180 min;最后硝酸、醋酸体积比为1∶3的混酸回流处理(固定反应固液比为1 g∶25 mL,处理时间为30 min)。得到硝酸乙醇纤维素含量和α-纤维素含量分别高达95%、87%以上的松木纤维素。在一定程度上解决了松木屑废料的再利用和环境污染问题,同时为纤维素来源又增添一新途径。 High purity pine cellulose was extracted from pine sawdust by alkalization twice and acidification once. The factors affecting the purity of pine cellulose in the process of alkalization and acidification were studied. The content of α-cellulose and nitric acid-ethanol cellulose in the high purity pine cellulose was determined. The extraction process of cellulose was analyzed by FT-IR and XRD. The results indicated that the optimal extraction conditions were as follows: the mass fraction of NaOH in the primary alkalization at 100 ℃ for 2 h was 6% ; the mass fraction of NaOH in the second ary alkalization at 100 ℃ for 3 h was 12% ; and the ratio of HNO3 and CH3COOH (V: V) in acidification at 100 ℃ for 30 min was 1 : 3. The contents of nitric acid-ethanol cellulose and α-cellulose in pine cellulose were 95% and 87% , respectively. The problems of recycled use and of environmental pollution of pine sawdust are solved to some extent and a new approach to obtaining cellulose is found as well.
出处 《纺织学报》 EI CAS CSCD 北大核心 2013年第12期1-7,共7页 Journal of Textile Research
关键词 松木屑 纤维素 提取 碱性化 pine sawdust cellulose extraction alkalization
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参考文献12

  • 1KLEMM D, HEUBLEIN B, FINK H P, et al. Cellulose : fascinating biopolymer and sustainable raw material[ J 1. Angew Chem Int Ed,2005,44:3358 -3393.
  • 2EICHHORN S J,DUFRESNE A, ARANGUREN M,et al. Review:current international research into cellulose nanofibres and nanocomposites[ J]. Journal of MaterialsScience ,2010,45 ( 1 ) : 1 - 33.
  • 3刘书钗.制浆造纸分析与检测[M].北京:化学工业出版社,2003.17-31.
  • 4CHEN W P,ANDERSON A W,HAB Y W. Brewer's spent grain and corn steep liquor as alternative culture medium substrates for proteinase production by Streptomyces malaysiensis AMT-3 [ J ]. Appl Environ Microbiol, 1979,37 ( 2 ) : 324 - 331.
  • 5DEMIRBAS A. Mechanisms of liquefaction and pyrolysis reactions of biomass [ J ]. Energy Convers Manage, 2000,41 ( 6 ) : 33 - 46.
  • 6YANG Haiping, YAN Rong, CHEN Hanping, et al. Characteristics of hemicellulose, cellulose and lignin pyrolysis[J]. Fuel,2007(86) :1781 - 1788.
  • 7杨睿,周啸,罗传秋,等.聚合物近代仪器分析[M].3版.北京:清华大学出版社.2010:130-131.
  • 8XIAO B,SUN X F, SUN R C. Chemical structural andthermal characterizations of alkali-soluble lignins and hemiceluloses and celulose from maize stems, rye straw and rice straw [ J ]. Polymer Degradation and Stability, 2001 (74) :307 -319.
  • 9SUN X F, SUN characterization celluloses from treatment [ J ] R C, BAIRD M S,et al. Isolation and of lignins, hemicelluloses, and wheat straw by alkaline peroxide Cellulose Chem Technol, 200337(3/4) :283 -304.
  • 10孙晓锋,王海洪,胡永红.秸秆纤维素的一步快速提取和水解[J].高等学校化学学报,2010,31(9):1901-1904. 被引量:17

二级参考文献32

  • 1武进,张昊,张军,何嘉松.纤维素在离子液体中的均相乙酰化及其选择性[J].高等学校化学学报,2006,27(3):592-594. 被引量:17
  • 2张俐娜 杜予民.[A]..第三届甲壳素化学与应用研讨会论文集[C].,2001..
  • 3JarvisM.. Nature[J], 2003, 426:611-612.
  • 4Colluns T.. Nature[ J], 2001,414:161-163.
  • 5Sun X. F. , Sun R. C. , Baird M. S.. Tomkinson J.. Cell Chem. Teehnol. [J] , 2003, 37 (3/4) : 283-304.
  • 6Sun X. F. , Xu F. , Wang Y. X. , Sun R. C. , Fowler P. , Baird M. S.. Carbohydr. Res. [J] , 2005, 340(1) : 97-106.
  • 7Sun X. F. , Sun R. C. , Fowler P. , Baird M. S.. Carbohyd. Polym. [J] , 2004, 5(4) : 379-391.
  • 8ZhuS., WuY. , Chen Q. , Yu Z. , WangC. , Jin S. , DingY. , Wu G.. Green Chem. [J], 2006, 8:325-327.
  • 9LILu(李露) LINZhang-Bi(林章碧) YANGXiao(杨潇) WANZhen-Zhen(万珍珍) CUIShu-Xun(崔树勋).科学通报,2009,54(9):1622-1625.
  • 10MyerlyR. C., NicholsonM. D., KatzenR., TaylorJ. M.. Chemtech.[J], 1981, 11(3): 186-197.

共引文献86

同被引文献23

  • 1株式理学会社.X射线衍射手册[M].东京:株式理学会社.2007:108-111.
  • 2Biswas A, Kim S, Selling G W, et al. Microwave-assis- ted synthesis of alkyl cellulose in aqueous medium[J]. Carbohydrate Polymers, 2013, 94(1) : 120-123.
  • 3Donges R. Non-ionic cellulose ethers[J]. Brit Polym J, 1990, 23(4): 315-326.
  • 4Heinze T, Pfeifer A, Sarbova V, et al. 3 (Propyl cel- lulose: cellulose ether with exceptionally low floceula- tion temperatureVJ. Polymer. Bulletin, 2011, 66(9): 1219-1229.
  • 5Kamitakahara H, Koschella A, Mikawa Y. Syntheses and comparison of 2, 6-Di-O-methyl celluloses from nat- ural and synthetic celluloses[J]. Macromolecllar Biosci- ence, 2008, 8(7). 690-700.
  • 6Shi X, Tan L, Xing j, et al. Synthesis of hydroxyethyl- cellulose-g-methoxypoly (ethylene glycol) copolymer and its application for protein separation in CE[-J. Jour- nal of Applied Polymer Science, 2013, 128(3)I 1995-2002.
  • 7Xiao B, Sun X F, Sun R C. Chemical structural and thermal characterizations of alkali-soluble lignins and hemiceluloses and celulose from maize stems, rye straw and rice straw[J-]. Polymer Degradation and Stability, 2001, 74(2). 307-319.
  • 8刘杰,王府梅.碱处理对含木棉纤维纱线形态结构和性能的影响[J].纺织学报,2009,30(12):55-60. 被引量:21
  • 9王芳,张开莲,王俊.积雪草挥发油的GC指纹图谱研究[J].华西药学杂志,2010,25(1):54-56. 被引量:12
  • 10赵莉,孙红文,何娜.水稻秸秆主要组分的提取及其对芘的吸附作用[J].环境科学,2010,31(6):1575-1580. 被引量:6

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