摘要
金属有机框架化合物是一类新颖的纳米孔结晶材料,其由金属离子或簇以强的配位键形式连接多种多样的有机配体构成.金属有机框架化合物的均一孔径、高比表面积和吸附亲和力等独特的结构特点使其在组装成具有优异性能的膜方面具有很强的吸引力.金属有机框架膜在基础理论和实际应用方面显示了巨大的潜力.本文主要介绍近年来关于金属有机框架膜的制备及其在分离、化学传感、催化和电化学中的应用等研究,同时指出了目前需要克服的问题.
Metal organic frameworks （MOFs） are emerging as an extensive class of novel nanoporous crystalline materials, the structure of which is composed of metal ions or clusters joined by a variety of organic linkers through strong coordination bonds. Unique properties of MOFs including uniform pore size, high surface areas and specific adsorption affinities make MOFs attractive for assembling into films with excellent performance. The field of MOF films bears a huge potential for both fundamental understanding and practical applications. This review reports on recent progress in MOF films synthesis and their corresponding applications in separation, chemical sensors, catalysis, and electrochemistry. Meanwhile, the challenges to be overcome have been identified.
出处
《中国科学：化学》
CAS
CSCD
北大核心
2013年第12期1748-1760,共13页
SCIENTIA SINICA Chimica
基金
国家重点基础研究发展计划(973项目,2012CB821700)
国家自然科学基金(20831002,20502024)资助
关键词
金属有机框架膜
分离
化学传感
催化
电化学
metal-organic framework film, separation, chemical sensors, catalysis, electrochemistry
