摘要
Edmondson和Mrozinski分别在1965和1983年合成了不饱和烯酸铜(Ⅱ)与单齿氮配体配合物,用EPR、IR和磁化率等数据确定其组成为双核配合物,其中羧基为二齿配体,α,β-不饱和烯酸铜(Ⅱ)与二齿杂环氮形成的三元配合物迄今未见报道,本文以甲醇作溶剂合成了标题化合物,室温下培养了单晶。
A detailed synthesis is described for complex of copperα-methylacrylate with 2,2' -bipyridine. Elementary analysis, thermal analysis, conductivity data, susceptibility, IR and UV-vis spectra indicate the complex as [Cu(CH2=C(CH3)COO)2(bipy)(H2O)]. The molecular structure of the title compound was determined by single crystal X-ray diffraction. The crystal is a monoclinic and the lattice parameters are: α=0. 6851(1) nm, 6=1. 7626(2) nm, c=1. 5553(1) nm,β=96. 52 (1)°.
出处
《高等学校化学学报》
SCIE
EI
CAS
CSCD
北大核心
1991年第10期1297-1299,共3页
Chemical Journal of Chinese Universities
基金
国家自然科学基金
关键词
铜配合物
不饱和烯酸
联吡啶
Copper α-Methylacrylate, 2,2' -Bipyridine,Ternary complex
