摘要
By the end of the year 2010, a total of 15 large tight gas fields have been found in China, located in the Ordos, Sichuan, and Tarim basins. The annual production and total reserves of these fields in 2010 were 222.5× 108 and 28657× 108 m3, respectively, accounting for 23.5% and 37.3%, respectively, of the total annual production and reserves of natural gases in China. They took a major part of all natural gas production and reserves in China. According to the analyses of 81 gas samples, the stable carbon and hydrogen isotopic compositions of tight gases in China have following characteristics: (1) Plots of δ13CI-δ13C2-δ13C3, δ13C1-C1/C2+3 and δ13C1-δ 13C2 demonstrate the coal-derived origin of tight gases in China; (2) For the primary alkane gases, both carbon and hydrogen isotopic values increase with increasing molecular mass, i.e., δ13C1〈δ13C2〈δ13C3〈δ13C4 and δ2HI〈δ2Hz〈δ2H3; (3) The isotopic differences of δ13C2-δ13C1, δ13C3-δ13C1, δ2H2-δ22Hl and cTZH3-62H1 decrease with in- creasing Ro (%) and C1/C1-4; (4) There are seven causes for the carbon and hydrogen isotopic reversal, however, the carbon and hydrogen isotopic reversal of tight gases in China is caused mainly by multiple stages of gas charge and accumulation.
By the end of the year 2010,a total of 15 large tight gas fields have been found in China,located in the Ordos,Sichuan,and Tarim basins.The annual production and total reserves of these fields in 2010 were 222.5×108and 28657×108m3,respectively,accounting for 23.5%and 37.3%,respectively,of the total annual production and reserves of natural gases in China.They took a major part of all natural gas production and reserves in China.According to the analyses of 81 gas samples,the stable carbon and hydrogen isotopic compositions of tight gases in China have following characteristics:(1)Plots of 13C1-13C2-13C3,13C1-C1/C2+3and 13C1-13C2demonstrate the coal-derived origin of tight gases in China;(2)For the primary alkane gases,both carbon and hydrogen isotopic values increase with increasing molecular mass,i.e.,13C1<13C2<13C3<13C4and2H1<2H2<2H3;(3)The isotopic differences of 13C2-13C1,13C3-13C1,2H2-2H1and 2H3-2H1decrease with increasing Ro(%)and C1/C1–4;(4)There are seven causes for the carbon and hydrogen isotopic reversal,however,the carbon and hydrogen isotopic reversal of tight gases in China is caused mainly by multiple stages of gas charge and accumulation.