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Optical Properties of WO3-PbO Tellurite Glasses Doped with Rare Earths

Optical Properties of WO3-PbO Tellurite Glasses Doped with Rare Earths
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摘要 The tellurium-based glasses TeO2, 85TeOz-15WO3, 85TeO2-10WO3-5Sm203, 77TeO2-20WO3-3Y203, 77TeO2-20WO3-3La203, 65TeO2-33WO3-2Er203 and 49TeO2-29.4WO3-19.6PbO-2Er203 have been prepared by melt quenching technique. Density and molar volume have been measured for the present glasses. Optical absorption studies are carried out on the glass system in the wavelength range of 200-900 nm. The compositions depend on different physical parameters such as density, molar volume and oxygen packing density will be discussed. Also, molar refraction (RM), calculated refractive index (n), metallization criterion (M), electronic polarizability of the oxide ion (to2"(Eopt) and optical basicity A^opt have been determined.
出处 《Journal of Chemistry and Chemical Engineering》 2014年第1期11-20,共10页 化学与化工(英文版)
关键词 Rare earth oxide optical basicity electronic polarizability energy gap. 碲酸盐玻璃 光学性质 稀土 掺杂 摩尔体积 堆积密度 二氧化碲 淬火工艺
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